Zobrazeno 1 - 10
of 119
pro vyhledávání: '"W. Kläui"'
Publikováno v:
Analytica Chimica Acta. 319:271-274
The extraction of lithium, sodium, potassium, magnesium and calcium ions with the oxygen tripod ligand cyclopentadienyltris (diethylphosphito-P)cobaltate(−1), [(C 5 H 5 )Co{P(O)(OC 2 H 5 ) 2 } 3 ] − has been studied as a function of pH and ligand
Publikováno v:
Journal of Organometallic Chemistry. 426:99-103
Addition of P(OMe) 3 to [Cp★RuOMe] 2 ( 1 ) gave the new Cp★ Ru complexes (Cp★RuOMe) 2 (P(OMe) 3 ) ( 2 ), Cp★Ru (P(OMe) 3 ) 2 OMe ( 3 ) and Cp★Ru(P(OMe) 3 ) 2 (PO(OMe) 2 ) ( 5 ). 3 was converted slowly into the hydride Cp★Ru(P(OMe) 3 ) 2 H
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 47:1614-1617
Cristallisation dans Pma2 1 avec a=18,195, b=9,436, c=11,316 A, Z=4; affinement jusqu'a R=0,036. Chaque groupement [(C 5 H 5 )Co{P(O)(OMe) 2 } 3 ] − constitue un coordinat pontant entre deux atomes Na. Le polyedre de coordination autour de l'ion Na
Publikováno v:
Physical Review B. 43:8196-8198
Observation d'un deplacement de l'equilibre chimique entre les etats de spin-bas et les etats de spin-haut des complexes octaedriques de Co 3+ en presence d'un champ magnetique applique, a l'aide d'une experience de transmission optique pour sonder l
Publikováno v:
Acta Crystallographica Section A Foundations of Crystallography. 52:C310-C310
Publikováno v:
Journal of Organometallic Chemistry. 280:C26-C30
Complexes of the type [(C 5 H 5 )Co{P(O)R 2 } 3 ] − , R = OCH 3 , OC 2 H 5 , react as tridentate oxygen ligands L − with [MBr(CO) 5 ], M = Mn, Re, in hexane or tetrahydrofuran to give the tricarbonyl derivatives [LM(CO) 3 ]. The slightly volatile
Publikováno v:
Journal of Organometallic Chemistry. 335:29-42
The air-stable, mixed main group-transition metal, trinuclear sandwich oxygen tripod 2/1 complexes, {η 5 -C 5 H 5 Co[P(OC 2 H 5 ) 2 O] 3 } 2 M, ( 1 , M = Sn): C 34 H 70 Co 2 O 18 P 6 Sn, a 18.871(12), b 22.461(12), c 12.671(7) A, β 92.53(5)°, mono
Publikováno v:
Journal of Organometallic Chemistry. 252:347-357
The synthesis of the phosphinito complexes [(C5H5)Co{P(O)R2}3Co{R2(O)P}3}Co(C5H5)] (R = C2H5 (Ib), CH2C6H5 (Id), C6H5 (Ie), p-C6H4Cl (If)), starting from secondary phosphine oxides and cobaltocene is described. Ib and Id are shown to react with cyani
Publikováno v:
Journal of Organometallic Chemistry. 253:45-52
(Cyclopentadienyl)tris(diethylphosphito- P )cobaltate(1-), [(C 5 H 5 )Co{P(O)-(OC 2 H 5 ) 2 } 3 ] − , reacts as an oxygen tripod ligand L − with (CH 3 CN) 3 M(CO) 3 (M = Cr, Mo, W) in water to produce the tricarbonyl complexes [LM(CO) 3 ] − . T
Autor:
W. Kläui
Publikováno v:
Nachrichten aus Chemie, Technik und Laboratorium. 28:751-751