Zobrazeno 1 - 10
of 98
pro vyhledávání: '"W. J. McGill"'
Publikováno v:
Journal of Applied Polymer Science. 101:1562-1569
The tensile properties of conventional and peroxide vulcanisates were studied over a range of crosslink densities at room temperature and at 90°C. At 90°C the tensile strength and elongation at break of vulcanisates of lower crosslink density are s
Publikováno v:
Journal of Applied Polymer Science. 101:2423-2430
Stress relaxation on cessation of extension and hysteresis were examined in conventional and peroxide vulcanizates over a range of crosslink densities at room temperature and at 90°C. The rate of relaxation decreases with an increase in temperature
Publikováno v:
Journal of Applied Polymer Science. 102:876-884
It is proposed that, when vulcanization is performed using peroxides, crosslinking leads to a simple network, whereas in conventional vulcanization crosslinking a partially interpenetrating polymer network (PIPN) is formed. Two unfilled polyisoprene
Publikováno v:
Journal of Applied Polymer Science. 86:1516-1531
Rubber and the model compound 2,3-dimethyl-2-butene (TME) are vulcanized with zinc dimethyldithiocarbamate [Zn2(dmtc)4] accelerated sulfur formulations. When heated in dry nitrogen, Zn2(dmtc)4 is stable at vulcanization temperatures. However, it show
Publikováno v:
Journal of Applied Polymer Science. 81:2587-2596
Gum compounds of polyisoprene were vulcanized with a number of different curing systems to give networks with crosslink densities in two different ranges. Stress–strain curves were obtained upon rapid (500 mm/min) and slow (0.5 mm/min) extension. I
Publikováno v:
Journal of Applied Polymer Science. 81:2565-2572
The crystallization of polyisoprene, vulcanized to various degrees of cure with tetramethylthiuram disulfide/sulfur and 2-bisbenzothiazole-2,2′-disulfide (MBTS)/sulfur formulations, was studied in a density column at −25°C. The densities of vulc
Publikováno v:
Journal of Applied Polymer Science. 82:3067-3073
To investigate its thermal stability and reactivity towards other accelerators dimethylammonium dimethyldithiocarbamate ((dma)dmtc) was heated at programmed heating rates in sealed and open pans in a differential scanning calorimeter and on a thermob
Publikováno v:
Journal of Applied Polymer Science. 81:2573-2586
Polybutadiene compounds, vulcanized to various degrees of cure, were crystallized in a density column at −16°C. The percentage crystallinity of vulcanizates was also determined by differential scanning calorimetry where samples, precooled at a pro
Publikováno v:
Journal of Applied Polymer Science. 82:3074-3083
Rubber and model compound 2,3-dimethyl-2-butene were vulcanized for various times with dimethylammonium dimethyldithiocarbamate [(dma)dmtc]-accelerated sulfur formulations in the absence of ZnO. Model compound systems were analyzed by HPLC, and no re
Autor:
W. J. McGill, B. Morgan
Publikováno v:
Journal of Applied Polymer Science. 76:1413-1421
2-Bisbenzothiazole-2,2′-disulfide (MBTS)-accelerated sulfur vulcanization in the presence of ZnO and bis(2-mercaptobenzothiazole)zinc(II) [Zn(mbt)2] was studied using 2,3-dimethyl-2-butene (TME) as a model for polyisoprene. Reactions were carried o