Zobrazeno 1 - 10
of 25
pro vyhledávání: '"W. J. DeJarlais"'
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 19:1135-1144
(E&Z)-10-Octadecenoic-13,14-d2, −14,15-d2, and −14,14,15,15-d4 acids were prepared by Wittig synthesis. (E&Z)-11-Octadecenoic-14,14,15,15,17,18-d6 acids were prepared by Wittig synthesis and by synthesis and reduction of 11-octadecynoic-14,14,15,
Publikováno v:
Journal of the American Oil Chemists' Society. 60:975-978
Acetonitrile (ACN) is shown to be an effective eluent in combina-tion with methanol (MeOH) or acetone for the rapid separation of polyunsaturated fatty acid methyl esters on a fully silver-loaded ion-exchange (XN1010) column. ACN-containing eluents t
Publikováno v:
Journal of the American Oil Chemists' Society. 65:1180-1184
The electrolysis of methyl oleate in acetic acid solution with LiClO4 as the supporting electrolyte was studied. Both stirred and pumped undivided cells were used with Pt electrodes. Constant current at 6, 8, 16 and 24 ma/cm2 current densities was us
Autor:
W. J. DeJarlais, E. A. Emken
Publikováno v:
Lipids. 21:662-665
A new method for the synthesis ofcis-3,cis-5- andtrans-3,cis-5-tetradecadienoic acids, pheromone constituents of the dermestid beetlesAttagenus elongatulus andA. megatoma, was developed. The syntheses are based upon the formation oftrans-2-tetradecen
Publikováno v:
Lipids. 21:589-595
Triglycerides of deuterium-labeled trans-11-, trans-11-cis-11- and cis-9-octadecenoic acid (11t-18:1-2H, 11c-18:1-2H) were simultaneously fed to two young adult male subjects. Plasma lipids from blood samples collected periodically for 48 hr were ana
Autor:
W. J. Dejarlais, E. A. Emken
Publikováno v:
Synthetic Communications. 10:653-660
ω-Acetylenic acids are valuable intermediates in the synthesis of long-chain acids. Their dimagnesium salts may be alkylated with 1-bromo-2-alkynes or 2-alkenes to synthesize many important naturally occurring fatty acids1–3. Also, internally-mono
Autor:
W. J. Dejarlais, E. A. Emken
Publikováno v:
Journal of Labelled Compounds and Radiopharmaceuticals. 15:451-460
Methyl esters of 11-octadecenoic-15, 16-d2, −15, 15, 16, 16-d4, and −10, 10, 15, 15, 16, 16-d6 acids were prepared by Wittig synthesis from intermediates derived from 11-bromoundecanoic acid and 7-chloro-3-heptyne. The dideuterated acid was prepa
Autor:
R. L. Johnson, Roger W. Roeske, H. R. Snyder, Richard W. Bush, D. Bruce Bright, W. J. DeJarlais
Publikováno v:
Journal of the American Chemical Society. 82:3128-3133
The action of polyphosphoric acid on acetophenone produces two crystalline yellow hydrocarbons (A and B) of the formula C32H24; other products isolated are benzoic acid, dypnone, and a yellow substance (C) melting above 300 deg . The lower-melting ye
Autor:
L. E. Gast, W. J. DeJarlais
Publikováno v:
Journal of the American Oil Chemists’ Society. 48:21-24
Tris(triphenylphosphine) chlororhodium in methanol produces nearly 95% conjugated dienes from methyl linoleate. The dienes are principally cis,trans- and cis,cis-conjugated. Since deuterium is introduced into the products when deuterated methanol is
Publikováno v:
Journal of the American Oil Chemists' Society. 44:652-655
Methyl esters from vernonia oil containingcis-12,13-epoxy-cis-9-octadecenoate were reacted with acetone in the presence of a boron trifluoride catalyst to yieldtrans-12,13-0-isopropylidene-9-ene derivative I. Epoxidation of the unsaturation followed