Zobrazeno 1 - 10
of 100
pro vyhledávání: '"W. Hill Harman"'
Publikováno v:
Molecules, Vol 25, Iss 13, p 3090 (2020)
Although molybdenum sulfide materials show promise as electrocatalysts for proton reduction, the hydrido species proposed as intermediates remain poorly characterized. We report herein the synthesis, reactions and spectroscopic properties of a molybd
Externí odkaz:
https://doaj.org/article/6b076879e5284e55b0d145862bdfc182
Publikováno v:
Dalton Transactions. 50:14855-14863
Transition metal interactions with Lewis acids (M → Z linkages) are fundamentally interesting and practically important. The most common Z-type ligands contain boron, which contains an NMR active 11B nucleus. We measured solid-state 11B{1H} NMR spe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d7c583208bc803fcdd8c809a35048ac7
https://doi.org/10.1039/d1dt02981a
https://doi.org/10.1039/d1dt02981a
Publikováno v:
Angewandte Chemie. 132:23711-23715
An endohedrally functionalized self-assembled Fe4 L6 cage complex can catalyze oxa-Pictet-Spengler cyclizations of tryptophols and various aldehyde derivatives, showing strong rate accelerations and size-selectivity. Selective molecular recognition o
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4b3ff7585cc3b14cedb176ddbc5ed46b
https://doi.org/10.1002/ange.202009553
https://doi.org/10.1002/ange.202009553
Autor:
Ethan A. Hill, Niklas B. Thompson, Margaret L. Kelty, W. Hill Harman, Laura A. Essex, Alex McSkimming
Publikováno v:
Organometallics. 39:2545-2552
Transition-metal arene complexes are important species in catalysis and arene functionalization. Certain electron-rich metal fragments are capable of binding arenes across two adjacent carbon atoms, inducing significant dearomatization through strong
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d05c377897c278da044dbde3e871d868
https://doi.org/10.1021/acs.organomet.0c00340
https://doi.org/10.1021/acs.organomet.0c00340
Autor:
W. Hill Harman, Jordan W. Taylor
Publikováno v:
Chemical Communications. 56:13804-13807
The water reactivity of the boroauride complex ([Au(B2P2)][K(18-c-6)]; (B2P2, 9,10-bis(2-(diisopropylphosphino)-phenyl)-9,10-dihydroboranthrene) and its corresponding two-electron oxidized complex, Au(B2P2)Cl, are presented. Au(B2P2)Cl is tolerant to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2737e13943d8534e1525556be76da037
https://doi.org/10.1039/d0cc05261b
https://doi.org/10.1039/d0cc05261b
Autor:
Jordan W. Taylor, W. Hill Harman
Publikováno v:
Chemical Communications. 56:4480-4483
The boron-centered reactivity of the diboraanthracene-auride complex [Au(B2P2)][K(18-c-6)]; (B2P2, 9,10-bis(2-(diisopropylphosphino)-phenyl)-9,10-dihydroboranthrene) with a series of organic carbonyls is reported. The reaction of [Au(B2P2)]- with for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bdc0e2209df50cac1796eb87269702a6
https://doi.org/10.1039/d0cc01142h
https://doi.org/10.1039/d0cc01142h
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(41)
Transition metal interactions with Lewis acids (M → Z linkages) are fundamentally interesting and practically important. The most common Z-type ligands contain boron, which contains an NMR active
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::99fb5cf193a77cf67d05457db1f4d6bf
https://pubmed.ncbi.nlm.nih.gov/34604875
https://pubmed.ncbi.nlm.nih.gov/34604875
Autor:
Song Xu, W. Hill Harman, Joseph Q Nguyen, William J. Evans, Laura A. Essex, Joseph W. Ziller, Phillip Farias
Publikováno v:
Dalton Transactions. 50:15000-15002
The combination of a boron Lewis acid and a decamethylsamarocene, specifically 9,10-Me2-9,10-diboraanthracene with (C5Me5)2SmII(THF)2, in toluene leads to cooperative reductive capture of N2. The product crystallizes as the salt, [(C5Me5)2SmIII(THF)2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::497254b162c2acee13e6e0cf4206ec15
https://doi.org/10.1039/d1dt03220h
https://doi.org/10.1039/d1dt03220h
Publikováno v:
Chemical Science. 10:9084-9090
Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparatio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bad9a2cbc4f40fd51ead76c6035c95bc
https://doi.org/10.1039/c9sc02792k
https://doi.org/10.1039/c9sc02792k
Autor:
Jordan W, Taylor, W Hill, Harman
Publikováno v:
Chemical communications (Cambridge, England). 56(89)
The water reactivity of the boroauride complex ([Au(B
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::83ba491e524d21847934006ec3d10654
https://pubmed.ncbi.nlm.nih.gov/33078792
https://pubmed.ncbi.nlm.nih.gov/33078792