Zobrazeno 1 - 10
of 13
pro vyhledávání: '"W. H. Kalus"'
Publikováno v:
Environmental Health Perspectives
We examined t-butylhydroquinone (t-BHQ) and t-butylquinone (t-BuQ), two of the major microsomal metabolites of the synthetic antioxidant butylated hydroxyanisole (BHA), for their ability to react with the xenobiotic arylamines aniline and N-methylani
Publikováno v:
Food Additives and Contaminants. 7:223-233
The reaction mixture and several products arising from the reaction of butylated hydroxyanisole (BHA) and nitrite in anaerobic aqueous acidic solution were separated and tested in the Salmonella mutagenicity test. Among the nine products separable by
Autor:
W. H. Kalus
Publikováno v:
Fresenius' Zeitschrift f�r Analytische Chemie. 289:198-201
Die Radiotracertechnik mit 35SO2 als Indicator wurde zur Bestimmung von Schwefeldioxid in wasrigen Modell-Losungen und einigen Lebensmitteln nach der Destillationsmethode angewandt. Die Parameter, welche die analytischen Ergebnisse beeinflussen, werd
Publikováno v:
Chemosphere. 16:2479-2485
Some known reaction products of the two commonly used food additives, sulfite and nitrite, were examined for mutagenicity using the Salmonella/mammalian-microsome test. Potassium nitrosodisulfonate, potassium aminetrisulfonate and potassium hydroxyla
Autor:
W. G. Filby, W. H. Kalus
Publikováno v:
Zeitschrift für Naturforschung B. 31:1372-1375
The mass spectra of some aryl hydrazines under electron impact are reported. In every case studied fragmentation occurs via fission of the weak hydrazyl N—N bond and hydrogen migration. Metastable ion data is presented in support of a proposed mech
Autor:
W. H. Kalus, W. G. Filby
Publikováno v:
Experientia. 32:1366-1368
It is shown that the reaction between vitamin K3 and sodium sulphite under physiological conditions leads to the formation of free radical intermediates.
Autor:
W. G. Filby, W. H. Kalus
Publikováno v:
Chemischer Informationsdienst. 7
Autor:
W. H. Kalus, W. G. Filby
Publikováno v:
Experientia. 36(2)
The participation of semiquinone free radicals during the reaction of ascorbic acid with acidified sodium nitrite has been demonstrated by ESR spectroscopy unambiguously for the first time. Scavenging of the nitrosating agent, reflected by the observ
Stopped flow ESR study of the action of carbohydrates on ascorbic acid oxidation in aqueous solution
Autor:
W H, Kalus, W G, Filby
Publikováno v:
International journal for vitamin and nutrition research. Internationale Zeitschrift fur Vitamin- und Ernahrungsforschung. Journal international de vitaminologie et de nutrition. 55(1)
The influence of added carbohydrate on the decay kinetics of the ascorbic acid free radical generated in deaerated aqueous solutions by the action of potassium ferricyanide on ascorbic acid has been studied. Addition of carbohydrate (less than or equ
Autor:
W H, Kalus, W G, Filby
Publikováno v:
International journal for vitamin and nutrition research. Internationale Zeitschrift fur Vitamin- und Ernahrungsforschung. Journal international de vitaminologie et de nutrition. 47(3)
The relative rate constants for the decay of ascorbate free radical in aqueous solutions in the presence of heavy metal ions, hydrogen peroxide and sulphite were measured the ESR-spectroscopy. The oxidation of ascorbic acid showed a strong pH depende