Zobrazeno 1 - 10 of 50 pro vyhledávání: '"W. C. E. Higginson"'
3
The mechanism of polymerisation reactions in liquid ammonia
Autor: M. G. Evans, W. C. E. Higginson, N. S. Wooding
Publikováno v: Recueil des Travaux Chimiques des Pays-Bas. 68:1069-1078
The polymerization of styrene, methyl methacrylate and acrylonitrile is initiated by the amide ion in liquid ammonia, the product being a low molecular weight polymer containing one NH2 group per polymer chain. Other negative ions such as the triphen
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a176922d0bd576f7b4e064a222e94109
https://doi.org/10.1002/recl.19490681108
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5
Kinetic studies of oxidation–reduction of cobalt–ethylenediaminetetra-acetic acid complexes. Part IV. The reduction of ethylenediaminetetra-acetatocobaltate(III) and related complexes by chromous ion
Autor: W. C. E. Higginson, P. B. Wood
Publikováno v: J. Chem. Soc. A. :1645-1652
The nature of the chromium(III) products in the reduction of various polycarboxylatocobalt(III) complexes by chromous ion in dilute perchloric acid solution has been studied and the approximate rates of these reactions found by a competition method.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5f9108680ef330ac32c80d230b79a842
https://doi.org/10.1039/j19660001645
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6
Some reactions of di-µ-hydroxo-bis{dioxalatocobaltate(III)} in aqueous solution
Autor: W. C. E. Higginson, Lee Hin-Fat
Publikováno v: J. Chem. Soc. A. :2589-2594
The kinetics of hydrolysis of di-µ-hydroxo-bis{dioxalatocobaltate(III)} to give dioxalatodiaquocobaltate(III) have been studied in aqueous solutions in the pH range 3·5–4·6. Under these conditions, cobalt(II) is the final product, but is formed
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8bcc0fbe5c8c31a13bbecc0c8305583c
https://doi.org/10.1039/j19710002589
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8
The catalyzed dehydration of acetaldehyde hydrate, and the effect of structure on the velocity of protolytic reactions
Autor: W. C. E. Higginson, Ronald Percy Bell
Publikováno v: Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. 197:141-159
The reaction CH 3 CH(OH) 2 →CH 3 CHO + H 2 O has been studied kinetically in aqueous acetone using a dilatometric method. It was found to be a first-order reaction, catalyzed by uncharged acids, cation acids, uncharged bases and anion bases. Quanti
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::b9a14019357081761e27e737621da12a
https://doi.org/10.1098/rspa.1949.0055
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10
The polymerization of epoxides by metal halide catalysts
Autor: Morton Litt, R. O. Colclough, W. C. E. Higginson, J. B. Jackson, Geoffrey Gee
Publikováno v: Journal of Polymer Science. 34:171-179
Ethylene, propylene, and styrene oxides have been polymerized by a range of metal halide catalysts, high molecular weight products being obtained from the two firstnamed. The limited quantitative evidence presented is consistent with the view that th
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1c726d82c7aee3f71dbdb5b2ffcc1f76
https://doi.org/10.1002/pol.1959.1203412715
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