Zobrazeno 1 - 10
of 41
pro vyhledávání: '"Vyacheslav V. Sushev"'
Autor:
Alexandra V. Khristolyubova, Georgii K. Fukin, Yu. S. Panova, Alexander N. Kornev, Vyacheslav V. Sushev, N. V. Zolotareva, M. D. Grishin, E. V. Baranov
Publikováno v:
Russian Chemical Bulletin. 70:1973-1986
Such ketazines as azines of acetophenone and its substituted derivatives (p-F, m-Cl, p-I, p-Me, p-OMe), acetone, dibenzyl ketone, propiophenone, and indan-2-one were studied in the reaction with phosphorus(ɪɪɪ) chloride. The possibility of the for
Autor:
Georgy K. Fukin, Alexandra V. Khristolyubova, Roman V. Rumyantcev, V. E. Galperin, Natalia V. Zolotareva, Vyacheslav V. Sushev, Alexander N. Kornev, Yulia S. Panova
Publikováno v:
Dalton Transactions. 50:5890-5898
Treatment of 3a,6a-diaza-1,4-diphosphapentalene (DDP) with an excess of PhBCl2 yields the corresponding bis(borane) adduct DDP(PhBCl2)2 (14), demonstrating the availability of two lone pairs on the phosphorus center. The reaction between DDP and B(C6
Autor:
Evgeny V. Baranov, Alexander N. Kornev, Georgy K. Fukin, Alexandra V. Khristolyubova, Vyacheslav V. Sushev, Natalia V. Zolotareva, Yulia S. Panova
Publikováno v:
New Journal of Chemistry. 45:18491-18496
The interaction of 1,4-dichloro-3a,6a-diaza-1,4-diphosphapentalenes with metallic Na or Li or the naphthalene-Na anion-radical salt in THF proceeds through several successive stages: dehalogenation, two types of rearrangement of the heteropentalene f
Autor:
A. V. Sheyanova, N. V. Zolotareva, Anton V. Cherkasov, Alexander N. Kornev, Yu. S. Panova, Vyacheslav V. Sushev
Publikováno v:
Russian Chemical Bulletin. 69:1897-1906
The reaction of benzophenone hydrazone with chlorodiphenylphosphine in the presence of triethylamine affords the monophosphino derivative Ph2C=N-N(H)PPh2(1). The lithiation of 1 with one equivalent of MeLi produces the stable salt Ph2C=N-N(Li)PPh2, a
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 195:905-909
This review article provides the reader with numerous evidence that 3a,6a-diaza-1,4-diphosphapentalenes are a form of existence of stabilized singlet phosphinidenes. In particular, the oligomerizat...
Autor:
Yu. S. Panova, A. V. Sheyanova, Alexander N. Kornev, E. V. Baranov, Gleb A. Abakumov, Georgy K. Fukin, Vyacheslav V. Sushev, V. E. Galperin
Publikováno v:
Russian Journal of Coordination Chemistry. 46:98-104
3a,6a-Diaza-1,4-diphosphapentalene (DDP) with indium triiodide forms the [In(DDP)I3] complex (I) with the ratio In : DDP = 1 : 1. The DDP ligand reacts with antimony(III) chloride to form a coordination polymer, the treatment of which with pyridine i
Autor:
Diego F. Dorado Daza, Anton V. Cherkasov, Alexander S. Novikov, Gleb A. Abakumov, Vyacheslav V. Sushev, Alexander N. Kornev, Yulia S. Panova, Georgy K. Fukin
Publikováno v:
Inorganic Chemistry. 58:16144-16153
The current study provides a clear understanding of the chemical properties of annelated 3a,6a-diaza-1,4-diphosphapentalenes (DDPs), which are best viewed as stabilized singlet phosphinidenes. It w...
Autor:
Vyacheslav V. Sushev, Alexander N. Kornev, E. V. Baranov, Gleb A. Abakumov, Yu. S. Panova, V. E. Galperin, Georgy K. Fukin
Publikováno v:
Russian Journal of General Chemistry. 89:51-58
The reaction of 3a,6a-diaza-1,4-diphosphapentalene with 1-bromo-2-phenylacetylene has led to the formation of 1,1-bis(phenylethynyl)- and 1,4-dibromo-3a,6a-diaza-1,4-diphosphapentalene. The first has been also prepared via a different route by the re
Autor:
Roman V. Rumyantcev, Natalia V. Zolotareva, Georgy K. Fukin, Yulia S. Panova, Vyacheslav V. Sushev, Alexander N. Kornev, Diego F. Dorado Daza
Publikováno v:
Inorganic chemistry. 59(16)
Herein, we present the synthesis, single-crystal X-ray structures, and spectroscopic properties for the 1:1 donor-acceptor complexes of 1,2,4,5-tetracyanobenzene (TCNB) with annelated 3a,6a-diaza-1,4-diphosphapentalenes (DDPs) based on cyclohexanone
Autor:
Vyacheslav V. Sushev, Gleb A. Abakumov, Alexander N. Kornev, Anton V. Cherkasov, V. E. Galperin, A. V. Arapova, Yu. S. Panova
Publikováno v:
Russian Chemical Bulletin. 67:2073-2078
The reaction of cyclohexane-annulated 3 a,6a-diaza-1,4-diphosphapentalene (DDP) with di-tert-butyl acetylenedicarboxylate (DBAD) affords the 1,3-dipolar cycloaddition product of the acetylene moiety to the phosphorus and sp2-carbon atoms of DDP in 90