Crystal structure of poly[[diaquatetra-μ2-cyanido-platinum(II)iron(II)] methanol 4/3-solvate]: a three-dimensional Hofmann clathrate analogue

Autor: Volodymyr M. Hiiuk, Vasyl Mykhailovych, Sergiu Shova, Irina A. Golenya, Il'ya A. Gural'skiy

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 78, Iss 2, Pp 216-219 (2022)

In the title polymeric coordination compound, {[FePt(CN)4(H2O)2]·1.33CH3OH}n, the FeII cation (site symmetry 4/mm.m) is coordinated by the N atoms of four cyanide anions (CN−) and the O atoms of two water molecules, forming a nearly regular [FeN4O

Externí odkaz: https://doaj.org/article/30a5035a487b4fdf80a3c7fe3d310223

Crystal structure of catena-poly[[[tetraaquairon(II)]-trans-μ-1,2-bis(pyridin-4-yl)ethene-κ2N:N′] bis(p-toluenesulfonate) methanol disolvate]

Autor: Volodymyr M. Hiiuk, Diana D. Barakhty, Sergiu Shova, Ruslan A. Polunin, Il'ya A. Gural'skiy

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 12, Pp 1977-1980 (2017)

In the title polymeric complex, {[Fe(C12H10N2)2(H2O)4](CH3C6H4SO3)2·2CH3OH}n, the FeII cation, located on an inversion centre, is coordinated by four water molecules in the equatorial positions and two 1,2-bis(pyridin-4-yl)ethene molecules in the ax

Externí odkaz: https://doaj.org/article/87f5e30bb2ea4839a53c56bdc802a7a0

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)

Autor: Volodymyr M, Hiiuk, Sergii I, Shylin, Diana D, Barakhtii, Dmytro M, Korytko, Volodymyr O, Kotsyubynsky, Aurelian, Rotaru, Sergiu, Shova, Il'ya A, Gural'skiy

Publikováno v: Inorganic chemistry. 61(4)

Two 2D Hofmann-type complexes of the composition [Fe(Phpz)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::6e5bfaa24573c99fe64647514e43daf6
https://pubmed.ncbi.nlm.nih.gov/35029111

Influence of the ultra-slow nucleation and growth dynamics on the room-temperature hysteresis of spin-crossover single crystals

Autor: A. A. Golub, Azzedine Bousseksou, Il'ya A. Gural'skiy, Gábor Molnár, Karl Ridier, Volodymyr M. Hiiuk, William Nicolazzi, Igor O. Fritsky

Publikováno v: Chemical Physics Letters
Chemical Physics Letters, Elsevier, 2021, 770, pp.138442. ⟨10.1016/j.cplett.2021.138442⟩
Chemical Physics Letters, 2021, 770, pp.138442. ⟨10.1016/j.cplett.2021.138442⟩

International audience; Nucleation and growth phenomena associated with the thermally-induced spin transition was studied using optical microscopy in single crystals of a cyanoheterometallic coordination polymer [Fe(1,6-naphthyridine)2(Ag(CN)2)2]. De

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::648eb52a11d3f729619ae01776a63bec
https://hal.archives-ouvertes.fr/hal-03179259

Room temperature hysteretic spin crossover in a new cyanoheterometallic framework

Autor: Aurelian Rotaru, Il'ya A. Gural'skiy, Vadim Ksenofontov, Sergiu Shova, Volodymyr M. Hiiuk, Igor O. Fritsky

Publikováno v: Chemical Communications

A new iron(II)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported. This complex exhibits a high reproducibility of the spin transition in many successive thermal cycles, stability of both spin states

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::52690495a4208e39a060aa850980a153
https://pubmed.ncbi.nlm.nih.gov/30816373