Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Volker Langenhahn"'
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 636:492-498
The highly functional chromio nitrile ylides Cr(CO)5C≡N–C(Cl)–PR3 (R = Ph, NMe2) (2a, b) form readily in mixtures of Cr(CO)5CNCCl3 (1) with the respective phosphanes. Their reactions without isolation with the acylating agent Cr(CO)5CN(C=O)Ar (
Autor:
Gerhard Zinner, Dieter Lentz, Gerhard Beck, Bernhard Herrschaft, Wolf Peter Fehlhammer, Volker Langenhahn
Publikováno v:
Journal of Organometallic Chemistry. 692:2936-2948
Under aprotic conditions, Cr(CO) 5 CNCCl 3 ( 1 ) reacts with triphenylphosphine in the presence of aromatic aldehydes or ketones to give the α-chloroalkenylisocyanide complexes cis ( Z )- and trans ( E )-Cr(CO) 5 CNCCl CRR′ {R = H, R′ = 4-C 6 H
Publikováno v:
Angewandte Chemie. 117:3825-3829
Autor:
Matthias Tamm, F. Ekkehardt Hahn, Volker Langenhahn, Lars Wittenbecher, Duc Le Van, Thomas Lügger
Publikováno v:
Heteroatom Chemistry. 13:540-549
The cyclization reaction of coordinated β-functional phenyl isocyanides was used to generate coordinated anellated N-heterocyclic carbenes. Coordinated 2-trimethylsiloxyphenyl isocyanide reacts, after SiO bond cleavage, to yield a complex with a coo
Publikováno v:
Chemical communications (Cambridge, England). (43)
Tungsten complex 5 with a coordinated 2-azidoethyl isocyanide ligand reacts with PMe3 at the azido function to give a complex with a coordinated iminophosphorane which upon hydrolysis of the PN bond yields a complex with an NH,NH-stabilized N-heteroc
Publikováno v:
Angewandte Chemie (International ed. in English). 44(24)
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 9(3)
The reaction of 2-azidophenyl isocyanide (7) with [M(CO)(5)(thf)] (M=Cr, W) yields the isocyanide complexes [M(CO)(5)(7)] (M=Cr 8, M=W 9). Complexes 8 and 9 react with tertiary phosphines such as triphenylphosphane at the azido function of the isocya
Publikováno v:
Angewandte Chemie; May2005, Vol. 117 Issue 24, p3825-3829, 5p
Publikováno v:
Chemical Communications; Oct2005, Vol. 2005 Issue 43, p5390-5392, 3p