Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Vlastimil Hruška"'
Autor:
Martin Ansorge, Milan Boublík, Gyula Vigh, Vlastimil Hruška, Michal Malý, Jana Šteflová, Bohuslav Gaš
Publikováno v:
ELECTROPHORESIS. 41:514-522
Fourteen low molecular mass UV absorbing ampholytes containing 1 or 2 weakly acidic and 1 or 2 weakly basic functional groups that best satisfy Rilbe's requirement for being good carrier ampholytes (ΔpKa = pKamonoanion - pKamonocation
Publikováno v:
Analytica Chimica Acta. 1085:126-135
Within the frame of the dynamic pH junction preconcentration technique in capillary electrophoresis, we introduce a novel approach based on the use of the pH boundary of a system zone for the preconcentration of general, multivalent, weak analytes in
Autor:
Martin, Ansorge, Bohuslav, Gaš, Milan, Boublík, Michal, Malý, Jana, Šteflová, Vlastimil, Hruška, Gyula, Vigh
Publikováno v:
Electrophoresis5 References. 41(7-8)
Fourteen low molecular mass UV absorbing ampholytes containing 1 or 2 weakly acidic and 1 or 2 weakly basic functional groups that best satisfy Rilbe's requirement for being good carrier ampholytes (ΔpK
Autor:
Michal Malý, Martin Ansorge, Jana Svobodová, Bohuslav Gaš, Vlastimil Hruška, Marijana Pocrnić, Milan Boublík, Kateřina Lorinčíková, Pavel Dubský
Publikováno v:
Electrophoresis6 References. 41(7-8)
Thermodynamic acidity constants (acid or acid-base dissociation constants, sometimes called also as ionization constants) and limiting ionic mobilities (both of them at defined temperature, usually 25°C) are the fundamental physicochemical character
Autor:
Gabriel S. Gerlero, Magda Dovhunová, Michal Malý, Vlastimil Hruška, Pavel Dubský, Pablo A. Kler, Martin Dvořák
Publikováno v:
Electrophoresis. 40(5)
The linear theory of electromigration, including the first-order nonlinear approximation, is generalized to systems with any equilibria fast enough to be considered instantaneous in comparison with the timescale of peak movement. For example, this th
Publikováno v:
Electrophoresis. 39(5-6)
The enantiomeric separation of methadone in the presence of multiple isomer mixtures of sulfated β-cyclodextrin (S-β-CD) was studied experimentally with CZE and theoretically using computer simulation. Experiments were performed over many years wit
Publikováno v:
ELECTROPHORESIS. 33:931-937
We introduce a computer implementation of the mathematical model of capillary zone electrophoresis described in the previous paper in this issue (Hruska et al., Electrophoresis 2012, 33), the program PeakMaster 5.3. The computer model calculates eige
Publikováno v:
ELECTROPHORESIS. 33:923-930
We extended the linearized model of electromigration, which is used by PeakMaster, by calculation of nonlinear dispersion and diffusion of zones. The model results in the continuity equation for the shape function ϕ(x,t) of the zone: ϕ(t) = -(v(0)
Simulation of the effects of complex- formation equilibria in electrophoresis: I. Mathematical model
Publikováno v:
ELECTROPHORESIS. 33:938-947
Simul 5 Complex is a one-dimensional dynamic simulation software designed for electrophoresis, and it is based on a numerical solution of the governing equations, which include electromigration, diffusion and acid-base equilibria. A new mathematical
Publikováno v:
The Journal of Physical Chemistry B. 113:12439-12446
Chemical oscillations are driven by a gradient of chemical potential and can only develop in systems where the substances are far from chemical equilibrium. We have discovered a new analogous type of oscillations in ternary electrolyte mixtures, whic