Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Vladimir L. Vyazovkin"'
Publikováno v:
Physical Chemistry Chemical Physics. 2:3797-3800
The decay kinetics of methyl radical isotopomers has been studied at 77 K in glassy mixtures xR′HOH+(1−x)CD3OH, where R′HOH is either CH3OH or C2H5OH. In matrices with a small fraction of H component (x⩽0.02) the CD3 radicals decay twice as q
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::00c168005dfb2bed13f5b7185ecec7de
https://doi.org/10.1039/b002210l
https://doi.org/10.1039/b002210l
Publikováno v:
Chemical Physics. 236:291-300
The kinetics of methyl radicals decay has been studied at 77 K and at 90 K in glassy mixtures 0.9(xC2H5OH+(1−x)C2D5OH)+0.1H2O. It has been shown that in matrices with a small content of H-component (x≲0.02) the decay rate of CD3 radicals is notic
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::db9ee399d5bcd06b549327a3e8cc1b91
https://doi.org/10.1016/s0301-0104(98)00172-4
https://doi.org/10.1016/s0301-0104(98)00172-4
Publikováno v:
Chemical Physics. 216:135-145
ESR technique has been used to study the kinetics of methyl radicals decay at 90K in glassy ethanol-1,2d5 with an admixture of diethyl ether and C2H5OH ethyl alcohol. It has been demonstrated that methyl radicals migrate freely throughout the sample.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1d214d301bd669fab14ad82a4d65fa55
https://doi.org/10.1016/s0301-0104(96)00354-0
https://doi.org/10.1016/s0301-0104(96)00354-0
Publikováno v:
Chemical Physics. 195:313-327
The ESR technique has been used to study the kinetics of the reaction of methyl and ethyl radicals with the additives of hydrogen-substituted alcohols CH3OH, C2H5OH, and CH3CD2OH, dissolved in glassy methanol-d3 within the temperature range 77–92 K
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::96115ec6ca7534ab1e7f93910ccbd7c3
https://doi.org/10.1016/0301-0104(95)00063-t
https://doi.org/10.1016/0301-0104(95)00063-t