Zobrazeno 1 - 10
of 46
pro vyhledávání: '"Vladimir I. Nevodchikov"'
Autor:
Herbert Schumann, Vladimir I. Nevodchikov, Igor L. Fedushkin, Sebastian Dechert, Mikhail N. Bochkarev
Publikováno v:
Russian Chemical Bulletin. 52:154-159
Reduction of 2,5-di-tert-butylcyclopentadienone with two equivalents of thulium diiodide in tetrahydrofuran afforded the binuclear thulium(iii) complex with the cyclopentadienyl oxide ligand, viz., TmI2(THF)2[η5-But2C5H2O]TmI2(THF)3 (1). Shielding o
Autor:
Yu. A. Kurskii, S. Müchle, Vladimir I. Nevodchikov, Mikhail N. Bochkarev, Igor L. Fedushkin, Herbert Schumann
Publikováno v:
Russian Chemical Bulletin. 51:160-169
ansa-Metallocenes (η5:η5-C24H16)M(THF)2 (M = Sm (1), Yb (2), Ca (3)) and (η5:η5-C24H16)MI(THF) (M = Dy (8), Er (9), Tm (10), Lu (11)) were prepared in 50—90% yields by the in situ reactions of two equivalents of potassium acenaphthylenide K+C12
Autor:
Vladimir K. Cherkasov, Gleb A. Abakumov, O. N. Mamysheva, Yu. V. Chechet, Vladimir I. Nevodchikov, Sergey A. Chesnokov
Publikováno v:
Russian Chemical Bulletin. 50:2366-2371
o-Benzoquinones initiate radical polymerization of methacrylates under visible light irradiation in the presence of tertiary amines. Spectral sensitivity of the initiating system coincides with absorption bands of o-benzoquinone attributed to the S(
Autor:
Tatyana V. Petrovskaya, Igor L. Fedushkin, Frank Girgsdies, Vladimir I. Nevodchikov, Mikhail N. Bochkarev, Herbert Schumann, Roman Weimann
Publikováno v:
Russian Chemical Bulletin. 49:1869-1876
Homoleptic 2,2′-bipyridyl complexes of lanthanides (Ln), Ln(bpy)4, were prepared by the reactions of iodides LnI2(THF)2 (Ln=Sm, Eu, Tm, or Yb), LnI3(THF)3 (Ln=La, Ce, Pr, Nd, Gd, or Tb), or bis(trimethylsilyl)amides Ln[N(SiMe3)2]3 (Ln=Dy, Ho, Er, o
Autor:
N. P. Makarenko, Vladimir I. Nevodchikov, Vladimir K. Cherkasov, N. A. Skorodumova, Ludmila G. Abakumova, Valentina N. Glushakova, Nikolay O. Druzhkov
Publikováno v:
Russian Chemical Bulletin. 48:934-937
Reaction of 3,6-di-tert-butyl-1,2-benzoquinone and 3,6-di-tert-butylcatechol withtert-butyl hydroperoxide in aprotic solvents leads to the generation of semiquinone (SQ.H), alkylperoxy (ROO.), and alkyloxy radicals. The reaction of SQ.H and ROO. prod
Autor:
V. K. Cherkasov, Ludmila G. Abakumova, Gleb A. Abakumov, N. N. Vavilina, Lev N. Zakharov, Vladimir I. Nevodchikov, Yu. A. Kurskii
Publikováno v:
Russian Chemical Bulletin. 48:350-355
Reactions of 3,6-di-tert-butyl-1,2-benzoquinone with PhC≡CLi and ButC≡CLi are multistage processes. In the first stage, nucleophilic 1,2-addition of the organometallic compound too-benzoquinone occurs to form the corresponding hydroxycyclohexadie
Autor:
Herbert Schumann, A. V. Protchenko, Mikhail N. Bochkarev, Igor L. Fedushkin, Vladimir I. Nevodchikov, Frank Girgsdies
Publikováno v:
Inorganica Chimica Acta. 280:138-142
Cp#2Yb (Cp#=C5H4(CH2)2NMe2) has been obtained by reaction of YbI2(THF)2 with 2 equiv. of C5H4(CH2CH2NMe2)K in THF. The X-ray structure analysis shows a bent structure with intramolecular coordination of both nitrogen atoms to ytterbium. The reaction
Autor:
Nikolay O. Druzhkov, Vladimir I. Nevodchikov, Yu. A. Kurskii, Gleb A. Abakumov, Lev N. Zakharov, Vladimir K. Cherkasov, Ludmila G. Abakumova
Publikováno v:
Russian Chemical Bulletin. 46:771-776
New di-o-quinones of the biphenyl series, namely, 2,2′-dialkyl-5,5′-di-tert-butylbiphenyl-3,4,3′,4′-diquinones, were synthesized. Their structures were established by IR and NMR spectroscopy. The molecular structure of 2,2′-dimethyl-5,5′-
Autor:
Gleb A. Abakumov, Yu. A. Kurskii, Nikolay O. Druzhkov, Vladimir K. Cherkasov, Vladimir I. Nevodchikov, Ludmila G. Abakumova, N. V. Zaitova
Publikováno v:
Russian Chemical Bulletin. 46:337-340
Base-catalyzed interaction of 3,6-di-tert-butyl-1,2-benzoquinone with malononitrile mainly occurs as 1,4-addition to give 3,6-di-tert-butyl-4-dicyanomethylpyrocatechol. Its oxidation leads to 3,6-di-tert-butyl-4-dicyanomethyl-1,2-benzoquinone, which
Autor:
Georgii K. Fukin, Gleb A. Abakumov, Vladimir K. Cherkasov, Yurii A. Kursky, Vladimir I. Nevodchikov, Nikolai O. Druzhkov, Alexandr V. Piskunov
Publikováno v:
Tetrahedron Letters. 46:4095-4097
The oxidation of 2-alkoxy-3,6-di-tert-butylphenols has been studied. It was found that 2-RO-3,6-di-tert-butylphenoxy radicals (R = Et, Pr, Ph) undergo dimerization by C–O coupling. The X-ray structure of 2-ethoxy-3,6-di-tert-butylphenoxy dimer has