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Autor:
Frank Schaper, Garry S. Hanan, Samik Nag, Viviane Friese, Jianhua Wang, Marie-Pierre Santoni, Alexandre Rodrigue-Witchel
Publikováno v:
European Journal of Inorganic Chemistry. 2011:39-44
A new N-heterocyclic carbene ligand N,N'-bis(2-pyridyl)-tetrahydropyrimidinium hexafluorophosphate (1) has been synthesized and characterized. Its homoleptic Ru II complex 2 exhibits a more facile oxidation (+1.17 V vs. SCE) relative to the prototypi