Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy(iii) complex

Autor: Pankaj Kalita, Naushad Ahmed, Shruti Moorthy, Virginie Béreau, Arun Kumar Bar, Pawan Kumar, Prakash Nayak, Jean-Pascal Sutter, Saurabh Kumar Singh, Vadapalli Chandrasekhar

Publikováno v: Dalton Transactions. 52:2804-2815

Synthesis, structural characterization and combined experimental and theoretical magnetic properties of a new homoaxially phosphine oxide coordinated pentagonal bipyramidal complex, [(LN3O2Ph)DyIII(Cy3PO)2]·[BPh4] are reported.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f8ffbf3a70edcd0acee34b5923d7abdf
https://doi.org/10.1039/d2dt03789k

Concomitant emergence of circularly polarized luminescence and single-molecule magnet behavior in chiral-at-metal Dy complex

Autor: Laurent Coolen, Jean-Pascal Sutter, Jiawen Liu, Bahjat El Rez, Yuki Horino, Virginie Béreau, Takayoshi Suzuki, Carine Duhayon

Publikováno v: Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers, 2020, 7 (22), pp.4527-4534. ⟨10.1039/D0QI00919A⟩
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (22), pp.4527-4534. ⟨10.1039/D0QI00919A⟩

International audience; Circularly polarized luminescence (CPL) was evidenced for the first time in single crystals of a chiral-at-metal Dy(III) single-molecule magnet. This CPL is opposite for the enantiomers and was found to appear and become stron

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3b162142a420222b7dd1c8b7497ba885
https://hal.science/hal-03035601

Molybdenum(III) Thiocyanate- and Selenocyanate-Based One-Dimensional Heteronuclear Polymers: Coordination Affinity-Controlled Assemblage of Mixed Spin and Mixed Valence Derivatives with Ni(II) and Co(II/III)

Autor: Jean-Pascal Sutter, Kateryna Bretosh, Malihe Mousavi, Carine Duhayon, Virginie Béreau

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2020, 59 (11), pp.7603-7613. ⟨10.1021/acs.inorgchem.0c00459⟩
Inorganic Chemistry, 2020, 59 (11), pp.7603-7613. ⟨10.1021/acs.inorgchem.0c00459⟩

International audience; One-dimensional coordination polymers constructed with the 4d metallo-ligand [Mo(NCS)6]3– associated with NiII and CoII complexes are reported. The first series consists of anionic NCS-bridged [Mo-MII]− coordination polyme

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1f654cadc3efc9c294771d67d51ce3f4
https://hal.archives-ouvertes.fr/hal-02749318/document

From heptacoordinated CrIII complexes with cyanide or isothiocyanate apical groups to 1D heterometallic assemblages with all-pentagonal-bipyramid coordination geometries

Autor: Carine Duhayon, Jean-Pascal Sutter, Céline Pichon, Bahjat Elrez, Virginie Béreau

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2018, pp.340-348. ⟨10.1002/ejic.201700845⟩

International audience; A series of heptacoordinated CrIII complexes with either cyano or thiocyanato ligands in the apical positions are described and their ability to act as metallo-ligands is illustrated. These compounds contain a pentadentate lig

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bb49d16a7b6d65911023dc7367d2880b
https://hal.archives-ouvertes.fr/hal-01962511

Tri- and pentanuclear NCS-bridged [MoIII–CuII] cluster compounds: Crystal structures and magnetic properties

Autor: Carine Duhayon, Virginie Béreau, Jean-Pascal Sutter, Maliheh Mousavi

Publikováno v: Polyhedron
Polyhedron, 2013, 65, pp.136-140. ⟨10.1016/j.poly.2013.08.020⟩

International audience; Two heteronuclear NCS-bridged compounds, namely [{Cu(3,3,3-tet)(CH3CN)}2{Mo(NCS)6}][Mo(NCS)6][PPh4]2·6CH3CN (1) and [{Cu(3,3,3-tet)(CH3CN)}4{Mo(NCS)6}][Mo(NCS)6]3[Cu(3,3,3-tet)(CH3CN)]2 (2) (with 3,3,3-tet = N,N-bis(3-aminopr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::22686e448964d929616f2939bb19e01c
https://doi.org/10.1016/j.poly.2013.08.020