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pro vyhledávání: '"Vincent J. Ovalle"'
Publikováno v:
Nature Catalysis. 5:624-632
Autor:
Vincent J. Ovalle, Matthias M. Waegele
Publikováno v:
The Journal of Physical Chemistry C. 124:14713-14721
The electrocatalytic reduction of carbon dioxide to hydrocarbons and oxygenates on Cu electrodes proceeds through surface-adsorbed CO. The adsorption and desorption of this intermediate play a key ...
Autor:
Vincent J. Ovalle, Matthias M. Waegele
Publikováno v:
The Journal of Physical Chemistry C. 123:24453-24460
Copper is the only pure metal electrocatalyst capable of converting carbon dioxide to hydrocarbons at significant reaction rates. However, the poor product selectivity of this process on copper rem...
Publikováno v:
ACS Catalysis. 8:7507-7516
Surface-adsorbed CO is generally considered a reactive on-pathway intermediate in the aqueous electrochemical reduction of CO2 on Cu electrodes. Though CO can bind to a variety of adsorption sites (e.g., atop or bridge), spectroscopic studies of the
Publikováno v:
Physical chemistry chemical physics : PCCP. 19(44)
The catalytic selectivity and reactivity of an electrocatalytic interface can profoundly depend on the identity of the supporting electrolyte's cation. In the case of CO2 reduction on copper electrodes, these cation effects have been utilized to supp