Zobrazeno 1 - 2
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pro vyhledávání: '"Vincent Gardon"'
Publikováno v:
Journal of Carbohydrate Chemistry. 16:113-127
Triphenylphosphine and diethyl azodicarboxylate react with 1,2-O-isopropylidene-α-D-xylo- (1) and ribofuranose (2) to give six-membered-ring phosphoranes. Xylofuranose 1 undergoes cyclodehydration to produce oxetane 17 in 85% yield, but ribofuranose
Publikováno v:
Carbohydrate Research. 245:233-244
4,6-Cyclo-4,6-dideoxy-hexopyranoses were obtained by palladium-mediated intramolecular cyclodehalogenation. Thus, methyl 2,3-di-O-acetyl-4,6-dideoxy-4,6-diiodo-β- d -galactopyranoside (3) afforded methyl 2,3-di-O-acetyl-4,6-cyclo-4,6-dideoxy-β- d -