Amidine-based ionic liquid analogues with AlCl3: a credible new electrolyte for rechargeable Al batteries

Autor: Lucio, Anthony J., Efimov, Igor, Efimov, Oleg N., Zaleski, Christopher J., Viles, Stephen, Ignatiuk, Beata B., Abbott, Andrew P., Hillman, A. Robert, Ryder, Karl S.

Here we demonstrate the generation of novel ionic liquid analogue (ILA) electrolytes for aluminium (Al) electrodeposition that are based on salts of amidine Lewis bases. The electrolytes exhibit reversible voltammetric plating/stripping of Al, good i

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https://zenodo.org/record/7896730

Amidine-based ionic liquid analogues with AlCl 3 : a credible new electrolyte for rechargeable Al batteries.

Autor: Lucio AJ; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Efimov I; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Efimov ON; Russian Acad. Sci., Inst. Prob. Chem. Phys., 1 Acad. Semenov Ave, Chernogolovka 142432, Moscow Region, Russia., Zaleski CJ; Wolfson School of Mechanical Electrical & Manufacturing Engineering, Loughborough University, Loughborough LE11 3TU, UK., Viles S; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Ignatiuk BB; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Abbott AP; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Hillman AR; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk., Ryder KS; Materials Centre, School of Chemistry, University of Leicester, Leicester LE1 7RH, UK. ajl71@le.ac.uk.

Publikováno v: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Sep 28; Vol. 57 (77), pp. 9834-9837. Date of Electronic Publication: 2021 Sep 28.