Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Vikentii I. Bragin"'
Autor:
Pavel V. Petrovskii, Vladimir I. Bregadze, Alexander A. Korlyukov, Igor B. Sivaev, Vikentii I. Bragin
Publikováno v:
Journal of Fluorine Chemistry. 142:14-18
Reactions of decaborane nido-B10H14 with a series of fluorobenzaldehydes in alkaline solution followed by treatment with iodine give the closo-[2-(X-FC6H4)-2-CB9H9]− anions (X = 2, 3, 4). Upon heating, these compounds rearrange to more thermodynami
Autor:
Alexander V. Prikaznov, Igor B. Sivaev, Pavel V. Petrovskii, Akim V. Shmal’ko, Vikentii I. Bragin, Vladimir V. Bregadze, Alexander V. Kisin
Publikováno v:
Polyhedron. 30:1494-1501
A series of new boron-containing carboxylic acids was prepared by the ring-opening reaction of cyclic oxonium derivatives of the closo -decaborate anion [B 10 H 10 ] 2− with methyl esters of hydroxybenzoic acids or the cyanide anion followed by hyd
Autor:
Elena A. Rakova, Sergey V. Timofeev, V. L. Shirokii, Vikentii I. Bragin, Zoya A. Starikova, Igor B. Sivaev, Vladimir I. Potkin, D. A. Rudakov, N. A. Maier, Vladimir I. Bregadze, Ivan A. Godovikov, Ivan V. Glukhov
Publikováno v:
Journal of Organometallic Chemistry. 692:5133-5140
Halogenation of 9-dimethylsulfonium-7,8-dicarba-nido-undecaborane [9-SMe2-7,8-C2B9H11] with N-chlorosuccinimide, bromine and iodine gave the expected corresponding halogen derivatives [9-SMe2-11-X-7,8-C2B9H10], where X = Cl (1), Br (2), I (3). In the
Publikováno v:
Russian Chemical Bulletin. 56:1918-1921
Comparative quantum chemical calculations of structural parameters, chemical shifts of 11B NMR spectra, and atomic charges in 10-vertex boron hydride anions [1-CB9H10]− and [1-B10H9N2]− were performed using the restricted Hartree-Fock method with
Autor:
Marina Yu. Stogniy, Irina A. Lobanova, Vikentii I. Bragin, Olga V. Sorokina, Ekaterina N. Abramova, Vladimir I. Bregadze, Pavel V. Petrovskii, Igor B. Sivaev, Viktoria N. Tsupreva
Publikováno v:
Collection of Czechoslovak Chemical Communications. 72:1676-1688
A new approach to synthesis of functional derivatives of 7,8-dicarba-nido-undecaborate anion based on ring-opening of its cyclic oxonium derivatives [10-(CH2)4O-7,8-C2B9H11] and [10-O(CH2CH2)2O-7,8-C2B9H11] with various nucleophiles was developed. Bo
Autor:
Vikentii I. Bragin, Alexander V. Prikaznov, Margarita N. Davydova, Igor B. Sivaev, Vladimir I. Bregadze
Publikováno v:
Collection of Czechoslovak Chemical Communications. 72:1689-1696
Synthesis of alkoxy derivatives of closo-decaborate anion [1- and 2-B10H9OR]2- by reaction of the hydroxy derivatives with corresponding alkyl bromides was described. A new method of synthesis of 2-hydroxy derivative of closo-decaborate anion [2-B10H
Autor:
Alexander V. Prikaznov, Igor B. Sivaev, Alexei A. Titov, Oleg A. Filippov, Vladimir I. Bregadze, Vikentii I. Bragin, Tatyana A. Teplinskaya, Pavel V. Petrovskii, Elena S. Shubina
Publikováno v:
Collection of Czechoslovak Chemical Communications. 72:1725-1739
The effect of electron-donating and electron-withdrawing substituents on the proton-deuterium exchange in derivatives of the closo-decaborate anion in methanol-d4 was studied. Introduction of the electron-donating hydroxy (alkoxy) group into the apic
Autor:
D. A. Rudakov, Vikentii I. Bragin, Vladimir I. Potkin, Pavel V. Petrovskii, A. V. Kisin, V. L. Shirokii, Igor B. Sivaev, Vladimir I. Bregadze, E. A. Dikusar
Publikováno v:
Russian Journal of Electrochemistry. 42:280-284
By electrochemical iodination of potassium 7-methyl-7,8-dicarba-nido-undecaborate and potassium 7,8-dimethyl-7,8-dicarba-nido-undecaborate, their monoiodine derivatives (extracted as tetramethylammonium salts) are synthesized. Their structure is conf
Autor:
Vikentii I. Bragin, N. A. Maier, D. A. Rudakov, Vladimir I. Bregadze, Pavel V. Petrovskii, Igor B. Sivaev, A. V. Kisin, V. L. Shirokii, Vladimir I. Potkin
Publikováno v:
Russian Chemical Bulletin. 54:1599-1602
Electrochemical thiocyanation of the dodecahydro-7,8-dicarba-nido-undecaborate and 7,8-dimethyldecahydro-7,8-dicarba-nido-undecaborate monoanions afforded thiocyanate derivatives of these compounds, which were isolated as alkylammonium salts. The str
Autor:
Vladimir I. Bregadze, Stefan Sjöberg, Vikentii I. Bragin, Natal'ya A. Votinova, Igor B. Sivaev
Publikováno v:
Russian Chemical Bulletin. 53:2092-2095
Reactions of an amino derivative of the closo-decaborate anion [1-B10H9NH3]− with aromatic aldehydes afforded Schiff bases [1-B10H9NH=CHAr]− (Ar=Ph, C6H4-2-OMe, or C6H4-4-NHCOMe). The reduction of the latter with sodium borohydride gave the corre