Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Victor J. Lillo"'
Publikováno v:
ARKIVOC, Vol 2010, Iss 3, Pp 29-44 (2009)
Externí odkaz:
https://doaj.org/article/dadbd6cf2af64a0e95df2ce278c00339
Publikováno v:
Noncovalent Interactions in Catalysis ISBN: 9781788014687
The main paradigm of today's chemistry is sustainability. In pursuing sustainability, we need to learn from chemical processes carried out by Nature and realize that Nature does not use either strong acids, or strong bases or fancy reagents to achiev
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::70b77fe0446c6fb2fcae3ea579968845
https://doi.org/10.1039/9781788016490-00066
https://doi.org/10.1039/9781788016490-00066
Autor:
José M. Saá, Victor J. Lillo
Publikováno v:
Chemistry - A European Journal. 22:17182-17186
Organocatalysts displaying a network of cooperative hydrogen bonds (NCHB) have been employed in an enzyme-like manner for a direct, switchable synthesis of enantiopure hexahydropyrimidinones (HHPMs) or dihydropyrimidinones (DHPMs) which starts at a c
Publikováno v:
Angewandte Chemie. 128:4384-4388
The concept of noncovalent organocatalysis by means of networks of cooperative hydrogen bonds (NCHB organocatalysis) has been explored. Arylideneureas were chosen as ideal substrates because of their powerful donor-acceptor properties. We have examin
Publikováno v:
ChemInform. 47
The concept of noncovalent organocatalysis by means of networks of cooperative hydrogen bonds (NCHB organocatalysis) has been explored. Arylideneureas were chosen as ideal substrates because of their powerful donor-acceptor properties. We have examin
Publikováno v:
Synthesis. 2010:1909-1923
Enantiomerically enriched trifluoromethyl-substituted alcoholshaving a quaternary center of chirality can be prepared by the catalyticenantioselective addition of carbon nucleophiles to trifluoromethylketones, trifluoropyruvates, or the like. In part
Publikováno v:
Tetrahedron Letters. 50:2266-2269
The reaction of biphenylene ( 1 ) with an excess of lithium powder (1:14 molar ratio) and a catalytic amount of DTBB (10 mol %) in THF at room temperature leads to the formation of the dilithiated species I by reductive opening of the four-membered r
Publikováno v:
ARKIVOC, Vol 2010, Iss 3, Pp 29-44 (2009)
The reaction of cyclopropylidene diphenylmethane 1 with an excess of lithium and a catalytic amount of naphthalene (5 mol %) at -20 oC, followed by addition of an electrophile [E = H2O, D2O, t-BuCHO, Me2CO, Et2CO, n-Pr2CO, i-Pr2CO, (c-C3H5)2CO, (CH2)
Publikováno v:
Tetrahedron Letters. 49:5182-5185
The reaction of 2,2-diphenylmethylenecyclopropane (5) with an excess of lithium and a catalytic amount of DTBB (4 mol %) in THF at −78 °C leads to the formation of dilithiated species 6–8 by reductive opening of the cyclopropane ring. Further re
Publikováno v:
Synthesis. 2008:1241-1248
The reaction of acenaphthylene with an excess of lithium powder and a catalytic amount of DTBB (7.5 mol%) in tetrahydrofuran at -70 °C followed by treatment with a carbonyl compound [Me 2 CO, Et 2 CO, I-Pr 2 CO, ( C-C 3 H 5 ) 2 CO, cyclopentanone, c