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pro vyhledávání: '"Vasu C. Sekhar"'
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :961-963
Values of ΔH‡ = 111.6 ± 0.3 kJ mol−1 (26.7 ± 0.1 kcal mol−1) and ΔS‡ = −25.7 ± 0.9 J K−1 mol−1 (−6.1 ± 0.2 cal K−1 mol−1) have been determined for the atropisomerization of (S)-3-(2-chlorophenyl)-2-[2-(6-diethylaminomethylpy
Publikováno v:
ChemInform. 21
The photokinetics of fragmentation reactions of [Ru3(CO)12] with L = PPh3, P(OPh)3, AsPh3, CO, 1-octene, and methyl acrylate in a variety of solvents have been studied. Quantum yields increase to limiting values at high [L] but the limiting values va
Publikováno v:
J. Chem. Soc., Dalton Trans.. :2145-2148
The kinetics of reactions of [Os3(CO)11(NCMe)] and [Os3(CO)10(NCMe)2] with P- or As-donor ligands in p-xylene or toluene have been studied and shown to be characteristic of reversible dissociative processes. In both cases MeCN is ca.10 times more nuc
Autor:
Vasu C. Sekhar, Anthony Poë
Publikováno v:
Inorganic Chemistry. 24:4376-4380
Cinetiques etudiees dans la decaline. Mecanismes des substitutions, parametres d'activation
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1933-1939
The photokinetics of fragmentation reactions of [Ru3(CO)12] with L = PPh3, P(OPh)3, AsPh3, CO, 1-octene, and methyl acrylate in a variety of solvents have been studied. Quantum yields increase to limiting values at high [L] but the limiting values va
Autor:
Anthony Poë, Vasu C. Sekhar
Publikováno v:
Chemischer Informationsdienst. 17
Cinetiques etudiees dans la decaline. Mecanismes des substitutions, parametres d'activation
Publikováno v:
ChemInform. 18
The kinetics of reactions of [Os3(CO)11(NCMe)] and [Os3(CO)10(NCMe)2] with P- or As-donor ligands in p-xylene or toluene have been studied and shown to be characteristic of reversible dissociative processes. In both cases MeCN is ca.10 times more nuc
Autor:
Vasu C. Sekhar, Anthony Poë
Publikováno v:
Chemischer Informationsdienst. 15
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1090-1091
The metal carbonyl clusters Me3(CO)12-n(PBun3)n(M = Os, n= 0–1, M = Ru, n= 1–2) react with PBun3 by bimolecular paths that involve fragmentation to mononuclear products, and that can be given the mechanistic.
Autor:
Vasu C. Sekhar, Anthony Poë
Publikováno v:
Journal of the American Chemical Society. 106:5034-5035
Cinetique de la reaction Os 3 (CO) 11 (η 1 -dppm)→Os 3 (CO) 10 (μ-dppm)-CO. Parametres d'activation