Výsledky vyhledávání - "Vasily V, Bashilov"

Peculiarities of the M–π interaction in phosphacymantrene derivatives upon the Mn(CO)3 fragment orientation: Experimental and theoretical electron density study

Autor: Fedor M. Dolgushin, Alexander F. Smol'yakov, A. G. Ginzburg, Mikhail Yu. Antipin, Vasily V. Bashilov

Publikováno v: Journal of Molecular Structure. 1014:81-91

The results of the single crystal X-ray diffraction analysis of 2,5-diphenylphosphacymantrene (η5-C4H2Ph2P)Mn(CO)3 (1) and experimental charge density distribution study of [(η4-C4H2Ph2P(O)H)Mn(СO)3]−[NH2Et2]+ (2) are discussed. The resultant de

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::27134f9e2a03e70243b29075fbee29bd
https://doi.org/10.1016/j.molstruc.2012.01.046

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Change of the coordination type for the phospholyl ligand under nucleophilic attack of H2O on phosphorus atom in 2,5-diphenylphosphacymantrene promoted by aliphatic amines

Autor: Vasily V. Bashilov, Fedor M. Dolgushin, Alexander F. Smol'yakov, A. G. Ginzburg, Viatcheslav I. Sokolov, Pavel V. Petrovskii

Publikováno v: Inorganica Chimica Acta. 370:292-296

η5-2,5-Diphenylphosphacymantrene (1) in benzene or CH2Cl2 solution does not react with amines. However, with amines NHEt2, NEt3, NEt(i-Pr)2 in excess and in the presence of small amounts of water 1 reacts to form anionic complexes [(CO)3Mn(η4-Ph2H2

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https://doi.org/10.1016/j.ica.2011.01.094

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Homolytic Reactive Mass Spectrometry of Fullerenes: Interaction of C60 and C70 with Organo- and Organoelement Mercurials in the Electron Impact Ion Source of a Mass Spectrometer; EPR, CIDEP, and MS Studies of Several Analogous Reactions of C60 Performed in Solution

Autor: Vasily V. Bashilov, Yury I. Lyakhovetsky, Yuri S. Nekrasov, Viatcheslav I. Sokolov, Boris Tumanskii, Elena A. Shilova

Publikováno v: The Journal of Physical Chemistry A. 113:13700-13710

Interaction of C60 with organo- and organoelement mercurials (CF3HgBr, PhHgBr, p-CH3C6H4HgBr, p-CH3OC6H4HgCl, CF3HgPh, Ph2Hg, (o-carborane-9-yl)2Hg, (m-carborane-9-yl)2Hg, (p-carborane-9-yl)2Hg, and (m-carborane-9-yl)HgCl) in the ionization chamber (

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https://doi.org/10.1021/jp906058q

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Novel optically active organometallic derivatives of fullerenes with non-central types of chirality in addends: synthetic and CD studies

Autor: A. G. Ginzburg, Viatcheslav I. Sokolov, Kyrill K. Babievsky, Fedor M. Dolgushin, Vasily V. Bashilov, Pavel V. Petrovskii, N. V. Abramova

Publikováno v: Tetrahedron Letters. 50:5347-5350

Palladium and platinum complexes of C 60 and C 70 possessing the enantiomeric ligand (−)-Bitianp with axial chirality and a pyrrolidino[60]fullerene bearing a planar chiral organometallic π-complex group in the heterocyclic ring have been synthesi

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https://doi.org/10.1016/j.tetlet.2009.07.009

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Trifluoromethylation of C60and C70with Mercury(II) Trifluoroacetate

Autor: Yury I. Lyakhovetsky, Roger Taylor, Elena A. Shilova, Yuri S. Nekrasov, Viatcheslav I. Sokolov, V Tatyana, Vasily V. Bashilov

Publikováno v: Fullerenes, Nanotubes and Carbon Nanostructures. 17:85-98

Fullerenes C60 and C70 are shown to react with Hg(CF3COO)2 in the ionization chamber of the electron impact source of a mass spectrometer at 300 and 310°C, yielding trifluoromethylated derivatives of the fullerenes with up to six and two CF3 addends

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https://doi.org/10.1080/15363830802674530

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Pentamethylated derivatives of [60]fullerene: X-ray structure of the C60Me5H and ESR spectroscopy evidence for the stable radical C60Me5

Autor: Boris Tumanskii, F. M. Dolgushin, V. I. Sokolov, Pavel V. Petrovskii, Vasily V. Bashilov

Publikováno v: Tetrahedron. 64:11291-11295

Single-crystal X-ray study of 6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro(C60-Ih)[5,6]fullerene (C60Me5H) has been reported. In crystal packing, the stacking self-organization of molecules is realized. It is concluded that the formation of such

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1ed365d056c850c22c49f07ebb5142e0
https://doi.org/10.1016/j.tet.2008.09.071

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Fullerene — Metallocene Composite Molecules: Different Types

Autor: Viatcheslav I. Sokolov, Vasily V. Bashilov, N. V. Abramova

Publikováno v: Fullerenes, Nanotubes and Carbon Nanostructures. 16:285-292

The results of synthesis and studies of C60 and C70 palladium complexes with metallocenyl or enantiomeric P‐ligands are summarized. Pyrrolidino[60]fullerenes with metallocenyl 2‐substituents derived from manganese, rhenium and cobalt also have be

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https://doi.org/10.1080/15363830802205731

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Synthesis and structure of the chiral palladium–fullerene C60 and C70 complexes with enantiomeric ligand 2,2′,5,5′-tetramethyl-4,4′-bis(diphenylphosphino)-3,3′-bithiophene [(−)tetraMe-BITIOP]

Autor: Viatcheslav I. Sokolov, Gianni Zotti, Vasily V. Bashilov, Tiziana Benincori, Pavel V. Petrovskii, Mara Sada, Feodor M. Dolgushin

Publikováno v: Journal of Organometallic Chemistry. 690:4330-4336

η 2 -Fullerene (C 60 and C 70 ) palladium optically active complexes with the axially chiral enantiomeric ligand of bithienyl series, [(−)tetraMe-BITIOP], have been synthesized and investigated by 31 P–{ 1 H} NMR, electronic spectroscopy, CD spe

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https://doi.org/10.1016/j.jorganchem.2005.07.003

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X-ray fluorescent spectroscopy and quantum chemistry investigation of electronic structure of the palladium[60]fullerene complex with bidentate ligand 1,1′-bis(diphenylphosphino)ferrocene

Autor: Lyubov G. Bulusheva, A. V. Gusel’nikov, Alexander V. Okotrub, V. D. Yumatov, V.I. Sokolov, Vasily V. Bashilov

Publikováno v: Journal of Molecular Structure. 749:193-199

The electronic structure of organometallic fullerene complex C60Pd(P(C6H5)2)2Fe(C5H4)2 has been investigated using X-ray fluorescent spectroscopy and density functional theory. It was shown that, the electronic state of carbon atoms incorporated into

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https://doi.org/10.1016/j.molstruc.2005.04.003

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Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands

Autor: Vasily V. Bashilov, Fedor M. Dolgushin, Kim P. Butin, Tatiana V. Magdesieva, D. N. Kravchuk, V. I. Sokolov

Publikováno v: Russian Chemical Bulletin. 53:795-799

Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum

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https://doi.org/10.1023/b:rucb.0000037844.93864.3c

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