Comparison of crystal structure and DFT calculations of triferrocenyl trithiophosphite’s conformance

Autor: Ruslan P. Shekurov, Mikhail N. Khrizanforov, Ilya A. Bezkishko, Tatiana P. Gerasimova, Almaz A. Zagidullin, Daut R. Islamov, Vasili A. Miluykov

Publikováno v: Beilstein Journal of Organic Chemistry, Vol 18, Iss 1, Pp 1499-1504 (2022)

A triferrocenyl trithiophosphite was studied by X-ray single-crystal diffraction. Triferrocenyl trithiophosphite has nine axes of internal rotation: three P–S bonds, three C–S bonds and three Fe–cyclopentadienyl axes. Rotation around the P–S

Externí odkaz: https://doaj.org/article/ae24ef875d3340f0a94324f77835f858

Synthesis, Structure, and Electrochemical Properties of 2,3,4,5-Tetraphenyl-1-Monophosphaferrocene Derivatives

Autor: Almaz A. Zagidullin, Alena R. Lakomkina, Mikhail N. Khrizanforov, Robert R. Fayzullin, Kirill V. Kholin, Tatiana P. Gerasimova, Ruslan P. Shekurov, Ilya A. Bezkishko, Vasili A. Miluykov

Publikováno v: Molecules, Vol 28, Iss 6, p 2481 (2023)

Heteroleptic 2,3,4,5-tetraphenyl-1-monophosphaferrocene [FeCp(η5-PC4Ph4)] was obtained at a 62% yield through the reaction of lithium 2,3,4,5-tetraphenyl-1-monophosphacyclopentadienide Li(PC4Ph4) (1) with [FeCp(η6-C6H5CH3)][PF6]. The structure of 1

Externí odkaz: https://doaj.org/article/15e3a85dc2244f68b7b20118115a52c5

Synthesis, structure and electrochemical properties of 3,4,5-triaryl-1,2-diphosphaferrocenes

Autor: Ilya A. Bezkishko, Almaz A. Zagidullin, Mikhail N. Khrizanforov, Tatiana P. Gerasimova, Kamil A. Ivshin, Olga N. Kataeva, Yulia S. Ganushevich, Vasili A. Miluykov, Peter Lönnecke, Evamarie Hey-Hawkins

Publikováno v: Inorganic Chemistry Frontiers. 9:2608-2616

New 3,4,5-triaryl-1,2-diphosphaferrocenes [FeCp(η5-P2C3R3)] have been extensively studied experimentally (NMR, UV-Vis, electrochemical studies, X-ray) and quantum chemically.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::53dc59688b5e5a423e0b8c97a09c618f
https://doi.org/10.1039/d2qi00446a

Sterically Hindered Quaternary Phosphonium Salts (QPSs): Antimicrobial Activity and Hemolytic and Cytotoxic Properties

Autor: Vadim V. Ermolaev, Daria M. Arkhipova, Vasili A. Miluykov, Anna P. Lyubina, Syumbelya K. Amerhanova, Natalia V. Kulik, Alexandra D. Voloshina, Valentine P. Ananikov

Publikováno v: International Journal of Molecular Sciences
International Journal of Molecular Sciences; Volume 23; Issue 1; Pages: 86
International Journal of Molecular Sciences, Vol 23, Iss 86, p 86 (2022)

Structure–activity relationships are important for the design of biocides and sanitizers. During the spread of resistant strains of pathogenic microbes, insights into the correlation between structure and activity become especially significant. The

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e74a62e347ff0e172ffcdf88d8344841
http://europepmc.org/articles/PMC8744835

Generation and direct EPR spectroscopic observation of triplet arylphosphinidenes: stabilisation

Autor: Eugenii Ya, Misochko, Alexander V, Akimov, Denis V, Korchagin, Yulia S, Ganushevich, Egor A, Melnikov, Vasili A, Miluykov

Publikováno v: Physical chemistry chemical physics : PCCP. 22(47)

Triplet phosphinidenes, which have been postulated as important intermediates in numerous organophosphorus reactions, have been previously directly observed only in isolated cases. Recently we have published the first recorded EPR spectrum of triplet

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e2dae955219455635831848ad94d1fdc
https://pubmed.ncbi.nlm.nih.gov/33283830