Structural Investigation of Magnesium Complexes Supported by a Thiopyridyl Scorpionate Ligand

Autor: Matthew P. Stevens, Emily Spray, Iñigo J. Vitorica-Yrezabal, Kuldip Singh, Vanessa M. Timmermann, Lia Sotorrios, Fabrizio Ortu

Publikováno v: Molecules, Vol 27, Iss 14, p 4564 (2022)

Herein, we report the synthesis of a series of heteroleptic magnesium complexes stabilized with the scorpionate ligand tris(2-pyridylthio)methanide (Tptm). The compounds of the general formula [Mg(Tptm)(X)] (1-X; X = Cl, Br, I) were obtained via prot

Externí odkaz: https://doaj.org/article/8da74247be4e4346bb5646832d0ddb43

Nanoscale Clustering of Alcoholic Solutes in Deep Eutectic Solvents Studied by Nuclear Magnetic Resonance and Dynamic Light Scattering

Autor: Odeh A. O. Alshammari, Andrew P. Abbott, Riina Häkkinen, Carmine D'Agostino, Vanessa M. Timmermann

Publikováno v: Häkkinen, R, Alshammari, O, Timmermann, V, D’agostino, C & Abbott, A P 2019, ' Nanoscale Clustering of Alcoholic Solutes in Deep Eutectic Solvents Studied by Nuclear Magnetic Resonance and Dynamic Light Scattering ', ACS Sustainable Chemistry & Engineering . https://doi.org/10.1021/acssuschemeng.9b03771
Häkkinen, R, Alshammari, O, Timmermann, V, D'Agostino, C & Abbott, A 2019, ' Nanoscale Clustering of Alcoholic Solutes in Deep Eutectic Solvents Studied by Nuclear Magnetic Resonance and Dynamic Light Scattering ', ACS Sustainable Chemistry & Engineering, vol. 7, no. 17, pp. 15086-15092 . https://doi.org/10.1021/acssuschemeng.9b03771

It was previously shown that water distributes heterogeneously in deep eutectic solvents (DESs). The aim of this study was to see whether this behavior was common to other hydrogen bonding compounds and determine when a solute formed an emulsion or a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f50e52c49b1d562de32761b61c3b7e01
https://doi.org/10.1021/acssuschemeng.9b03771