Co-existence of ferro- and antiferromagnetic interactions in a hexanuclear mixed-valence CoIII2MnII2MnIV2 cluster sustained by a multidentate Schiff base ligand

Autor: Oleh Stetsiuk, Vladimir N. Kokozay, Miguel Julve, Joan Cano, Benoit Fleury, Narcis Avarvari, Abdelkrim El-Ghayoury, Svitlana R. Petrusenko, Francesc Lloret, Valentyn Synytsia

Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2019, 48 (31), pp.11862-11871. ⟨10.1039/c9dt02503k⟩

The successful utilization of the “direct synthesis” approach yielded the unprecedented hexanuclear complex of formula [Co2MnII2MnIV2(L1)4Cl2(μ3-O)2(dmf)4]·2dmf (1) (H3L is the Schiff base derived from the condensation of salicylaldehyde and 3-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1414b26049c97b5dea93faeac15424f8
https://doi.org/10.1039/c9dt02503k