Construction of C‐N Atropisomers by Aminocatalytic Enantioselective Addition of Indole‐2‐carboxaldehydes to o ‐Quinone Derivatives

Autor: Vasco Corti, Mathias Kirk Thøgersen, Valdemar Juel Enemærke, Nomaan M. Rezayee, Casper L. Barløse, Karl Anker Jørgensen

Publikováno v: Corti, V, Thøgersen, M K, Enemærke, V J, Rezayee, N M, Barløse, C L & Anker Jørgensen, K 2022, ' Construction of C-N Atropisomers by Aminocatalytic Enantioselective Addition of Indole-2-carboxaldehydes to o-Quinone Derivatives ', Chemistry-A European Journal, vol. 28, no. 60, e202202395 . https://doi.org/10.1002/chem.202202395

The first atroposelective aminocatalytic methodology for the construction of C−N atropisomers is presented. The synthesis of this class of axially chiral molecules typically encompasses substrates in which the C−N bond is pre-formed. In contrast,

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https://doi.org/10.1002/chem.202202395