Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Valérie Arnaudinaud"'
Publikováno v:
Scopus-Elsevier
This article compiles our results in the field of flavonoid chemistry with the aim to synthesise isotopically labelled products. Two strategies (C 6 + C 3 –C 6 vs C 6 –C 2 + C 1 –C 6 ) and some organometallic (Pd 0 , Mo IV ) couplings were expl
Publikováno v:
Scopus-Elsevier
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In this paper gram-scale asymmetric total syntheses of pure (+)-4-[13C]catechin (1) and (−)-4-[13C]epicatechin (2) are described. Labelling was introduced through acylation of a phloroglucinol derivative 4 by 1-[13C]acetic acid, after activation by
Autor:
Jean-François Peyrat, Gérard Deffieux, A. Nuhrich, Joseph Vercauteren, Bastien Nay, Valérie Arnaudinaud, Jean-Michel Mérillon
Publikováno v:
European Journal of Organic Chemistry. 2000:1279-1283
Racemic 4-[13C]catechin 14 has been synthesized in ten steps starting from potassium [13C]cyanide. The intermediate chalcone 9 was formed by acylation of the benzylated phloroglucinol 7 with the caffeic acid synthon 6, using the trifluoroacetic mixed
Autor:
A. Nuhrich, Joseph Vercauteren, Jean-Pierre Monti, Gérard Deffieux, Bastien Nay, Sarah Vergé, Valérie Arnaudinaud, Jean-Michel Mérillon
Publikováno v:
Tetrahedron Letters. 42:5669-5671
Gram amounts of 13C-labelled dimer (−)-procyanidin B3 5 were prepared from 1-[13C]acetic acid by coupling the optically labelled flavan-3,4-diol (+)-7 with protected natural catechin (+)-3 in acidic medium.
Autor:
A. Nuhrich, Jean-Michel Mérillon, Bastien Nay, Gérard Deffieux, Valérie Arnaudinaud, Joseph Vercauteren, Jean-Pierre Monti
Publikováno v:
Tetrahedron Letters. 42:1279-1281
The regioselectively 13C-labelled (−)-procyanidin B3 was prepared in eight steps from 1-[13C]-acetic acid.
Autor:
Bénédicte, Berké, David, Vauzour, Chantal, Castagnino, Valérie, Arnaudinaud, Bastien, Nay, Catherine, Chèze, Joseph, Vercauteren
Publikováno v:
Journal de pharmacie de Belgique. 58(3)
Publikováno v:
ChemInform. 34