Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Valérie Abada"'
Publikováno v:
Polyhedron. 18:3497-3504
The addition of pinacol to mixtures of titanium and cerium isopropoxides as well as the use of insoluble titanium and cerium pinacolate synthons was investigated as a route to M-Ce (M=Ti, Nb) species. Pinacol was able to promote the formation of mixe
Publikováno v:
Polyhedron. 18:845-850
The reactions between niobium alkoxides [Nb(OR)5]2 (R=Pri, Et) and pinacol HOCMe2CMe2OH (pinH2) were investigated in different stoichiometries in toluene at room temperature. Nb4O4(pin)2(OPri)8 (1), [Nb2O(pin)4H2(OPri)2]m (2) and Nb3O3(pin)6H (3) wer
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3437-3442
The reaction between the cerium isopropoxide [Ce2(OPri)8(PriOH)2] and hexafluoroisopropyl alcohol (Hhfip) in THF at room temperature resulted in the formation of [Ce(hfip)4(THF)2(PriOH)x]. More stable compounds namely [Ce(hfip)4(diglyme)], [Ce(hfip)4
Publikováno v:
Polyhedron. 16:581-585
The reaction between [Nb(OPr i ) 5 ] 2 and methacrylic acid [CH 2 C(CH 3 )CO 2 H-McOH], and subsequent controlled microhydrolysis, gave [Nb 4 (μ-O) 4 (μ, η 2 -Mc) 4 (OPr i ) 8 ] which was characterized by X-ray diffraction. The compound is based o
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2407-2408
The reaction between niobium isopropoxide and 2-hydroxyethylmethacrylate (HEMA) at room temperature (1∶1 stoichiometry) afforded [Nb4(µ,η1,η2-OC2H4O)2(µ3,η1,η2-OC2H4O)2(µ-OC2H4O)(OPri)10] as characterized by X-ray diffraction.
Publikováno v:
Journal of the Chemical Society, Dalton Transactions (1470479X); 1999, Issue 15, p2407-2408, 1p
Publikováno v:
Journal of the Chemical Society, Dalton Transactions (1470479X); 1998, Issue 20, p3437-3442, 1p