Zobrazeno 1 - 10
of 46
pro vyhledávání: '"V.V. Severnyi"'
Publikováno v:
Polymer Science U.S.S.R.. 18:593-597
The kinetics of decomposition of dicumyl peroxide (DP) in solution in oligovinylorganosiloxanes and in oligosiloxanes free from vinyl groups, over the range of temperatures of 130–200°C, have been studied for the first by mass spectrometry. The en
Publikováno v:
Polymer Science U.S.S.R.. 16:488-494
A study was made of the behaviour of polymers prepared by poly-addition and containing siloxane bonds and crosslinking disylthylene groups. Quantitative relations were derived between the degree of hardening of polymers and their functionality. It wa
Publikováno v:
Polymer Science U.S.S.R.. 18:1464-1471
The curing of low molecular weight organo-silicon rubbers in the presence of tetra-ethoxysilane and tin diethyldicaprylate was found to take place only when traces of moisture were present; its rate is a linear function of the contents of curing agen
Publikováno v:
Polymer Science U.S.S.R.. 19:42-49
Vulcanization of “one-pack” organosilicon compositions occurring under the influence of atmospheric moisture is examined from the point of view of the theory of three dimensional polycondensation. The range of conditions for gel formation found e
Publikováno v:
Polymer Science U.S.S.R.. 18:1413-1417
Taking oligomethylvinyldimethylsiloxane as an example the kinetics of polymerization of oligovinylsiloxanes in the temperature interval of 150–200° in the presence of various amounts of initiator (dicumyl peroxide), have been studied by infrared s
Publikováno v:
Polymer Science U.S.S.R.. 29:1159-1163
The activity of organofunctional organosilicon crosslinking agents in the curing of linear-ladder type polyorganosiloxanes has been investigated. Using the obtained rate constants a quantitative analysis of the activity of the crosslinking agents may
Autor:
N.I. Trofimova, O.F. Aleksashina, N.V. Oleinik, V.v. Severnyi, T.I. Sunekants, V.G. Shigorin, V.V. Lyashevich
Publikováno v:
Polymer Science U.S.S.R.. 30:2021-2030
The effect of γ-irradiation in air and under vacuum at a temperature of about 30°C on a series of polyorganosiloxanes containing siloxadihydrophenanthrenyl units and lacquer coatings based on them is studied. It is found that the polymers studied b
Publikováno v:
Polymer Science U.S.S.R.. 30:1941-1947
The process of crosslinking of polyorganosiloxane block copolymers with a linear-ladder structure has been studied demonstrating that it is accompanied by reactions of cyclization and homofunctional condensation of the silanol groups of the polymer.
Publikováno v:
Polymer Science U.S.S.R.. 19:1775-1783
A study has been made of the reactivity of organofunctional alkoxysilanes used as crosslinking agents (CA) in the “cold” curing of α,ω-dihydroxypolydimethylsiloxane in the presence of organotin compounds. A kinetic equation relating the rate of
Publikováno v:
Polymer Science U.S.S.R.. 15:2049-2056
Turbidimetric titration is used to study the effect of the temperature and of the pH of the medium on the chemical composition of the hydrolysis products of methylphenyl- and methylvinyldichlorosilane polycondensates, with differing molar ratios. The