Zobrazeno 1 - 8
of 8
pro vyhledávání: '"V. Yu. Mashkin"'
Publikováno v:
Reaction Kinetics & Catalysis Letters. 47:119-123
Kinetic studies of tetrahydrofuran reaction with H2S were carried out in a flow-circulation reactor. Presumably, the reaction takes place through dissociative chemisorption of reactants and the interaction of surface structures formed to produce thio
Autor:
V. M. Kudenkov, V. Yu. Mashkin
Publikováno v:
Reaction Kinetics & Catalysis Letters. 46:263-269
Kinetic regularities of dimethyl sulfide synthesis from methanol and H2S in the presence of WO3/Al2O3 have been studied under gradientless conditions. A stepwise mechanism of the reaction is suggested implying that methanol methoxylates the catalyst
Autor:
S. N. Koshelev, V. Yu. Mashkin
Publikováno v:
Reaction Kinetics & Catalysis Letters. 46:187-192
Kinetic regularities of methylmercaptan production from dimethyl sulfide and H2S in the presence of γ-Al2O3 have been studied under gradientless conditions. A stepwise reaction mechanism is suggested implying that the catalyst surface is methoxylate
Publikováno v:
Reaction Kinetics & Catalysis Letters. 45:93-99
The kinetics of the reaction of methanethiol with methanol has been studied under gradientless conditions. A mechanism is postulated according to which, under the effect of methanol the surface is rapidly methoxylated and then CH3O groups react with
Publikováno v:
Reaction Kinetics & Catalysis Letters. 44:475-481
Kinetic regularities in catalytic disproportionation of methanethiol to dimethyl sulfide and hydrogen sulfide have been studied in a flow circulation reactor. A kinetic equation is suggested to describe the reaction on inhomogeneous surfaces.
Publikováno v:
Reaction Kinetics and Catalysis Letters. 3:105-113
The degree of uncertainty in the parameters of a kinetic model resulting from the experimental erros is discussed. For this purpose, the concept of interval estimation of the parameters is introduced and a method given for their determination. The me
Publikováno v:
Reaction Kinetics and Catalysis Letters. 22:293-297
Kinetic studies of unsteady- and steady-state oxidative dehydrogenation of n-butylenes indicate that in unsteady-state conditions the diffusion of oxygen ions out of the catalyst bulk plays a significant part. The parameters of the unsteady-state kin
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