Zobrazeno 1 - 10
of 57
pro vyhledávání: '"V. Ya. Fain"'
Publikováno v:
Russian Journal of Organic Chemistry. 49:696-701
Keto-enol and amine-imine tautomerism and equilibria with trans-conformers are characteristic of 1-(alkyl,aryl)amino-4-hydroxy-9,10-anthraquinones. Amino forms possess 1,10- and 1,4-, but not 9,10-quinoid structure. Various tautomeric and conformeric
Publikováno v:
Russian Journal of Physical Chemistry A. 87:623-627
Based on the example of 1,4,5,8-tetraamino-9,10-anthraquinone, a method is described for establishing the tautomeric compositions and sequences of tautomeric transformations that occur in known samples of quinones. An analysis of electronic absorptio
Publikováno v:
Russian Journal of General Chemistry. 83:485-491
Compounds widely known as 1,4-bis(alkylamino)-9,10-anthraquinones are in fact neither individual substances nor substituted 9,10-anthraquinones but equilibrium mixtures of tautomers. Their aminoimine tautomeric transformations follow the sequence 4,9
Publikováno v:
Russian Journal of General Chemistry. 82:1558-1566
Structure and amino-imine tautomerism of α-aminoanthraquinones, 1,5-and 1,8-diaminoanthraquinones, as well as 1,4,5-triamino-9,10-anthraquinones was studied. We found that in the study of properties of the compounds prone to tautomeric transformatio
Publikováno v:
Russian Journal of Organic Chemistry. 48:667-675
The fine structure of the πl,π*-absorption of hydroxyanthraquinones solutions in sulfuric acid arises due to the existence of the protonated forms as equilibrium mixtures of tautomers and conformers distinguished by the positions of the π-bonds, c
Publikováno v:
Russian Journal of Organic Chemistry. 48:376-382
Chemistry of 9,10-anthraquinones is considered as chemistry of isomeric anthraquinones existing in dynamic equilibrium with each other. Diversity of electronic absorption spectra of the same compounds is determined by tautomeric transformations. Aliz
Publikováno v:
Russian Journal of General Chemistry. 80:2470-2477
The products of reaction of α-hydroxyanthraquinones with boric acid are mixtures of 9,10-, 1,10 -, 1,4- and 1,5-quinoid tautomeric complexes of boric acid and borate esters differing by the coordination bonds with carbonyl groups existing in the dyn
Publikováno v:
Russian Journal of General Chemistry. 80:1986-1995
Existing views on the deprotonation and complexation of 1-amino-4-hydroxyanthraquinone are wrong. This compound, its anions, and complexes with metals are not individual substances, but they form a dynamic equilibrium mixture of keto-enol (keto-oxide
Publikováno v:
Russian Journal of Coordination Chemistry. 36:396-400
Diversity of electronic absorption spectra of the metal complexes with 1-amino-4-hydroxyan-thraquinone is a consequence of the fact that they exist as equilibrium mixtures of tautomers with the isomeric quinoid structure of the ligand. These complexe
Publikováno v:
Russian Journal of Organic Chemistry. 46:655-660
The disperse dye red 2C regarded as 1-amino-4-hydroxy-9,10-anthraquinone is not a 9,10-anthraquinone derivative. It is characterized by a keto-enol and amino-imine tautomerism, and it consists of equilibrium mixtures of tautomers and conformers conta