Zwitterionic π-coordination compounds of copper(I) with monosubstituted alkynes: synthesis, crystal and electronic structure of two copper(I) halide π-complexes with 4-amino-1-propargylpyridinium

Autor: Borys Mykhalichko, V. V. Kinzhybalo, G. V. Noshchenko

Publikováno v: Journal of Coordination Chemistry. 74:955-968

Crystals of two mononuclear π-coordination compounds of copper(I) halide with 4-amino-1-propargylpyridinium cation – [(HC≡CCH2NC5H4NH2)CuBr2] (1) and [(HC≡CCH2NC5H4NH2)CuCl1.61 Br0.39] (2) – were obtained in the CuX–H2O–(HC≡CCH2NC5H4 N

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https://doi.org/10.1080/00958972.2020.1869727

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Autor: Rok M; Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383 Wroclaw, Poland. magdalena.rok@chem.uni.wroc.pl., Prytys JK; Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383 Wroclaw, Poland. magdalena.rok@chem.uni.wroc.pl., Kinzhybalo V; Institute of Low Temperature and Structure Research, Polish Academy of Science, Okólna 2, PO Box 937, 50-950 Wroclaw, Poland., Bator G; Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383 Wroclaw, Poland. magdalena.rok@chem.uni.wroc.pl.

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