Zobrazeno 1 - 7
of 7
pro vyhledávání: '"V. P. Strunin"'
Publikováno v:
Reaction Kinetics and Catalysis Letters. 5:37-41
The influence of non-equilibrium vibrational excitation of CH3F molecules on the rate of their reaction with bromine atoms has been investigated. A three-fold increace in the reaction rate has been registered at CH3F and Br2 pressures of 0.07 Torr an
Publikováno v:
Reaction Kinetics and Catalysis Letters. 3:97-104
The ratio of the rate constants has been measured for the reaction of atomic chlorine with CH4 and CD4 within the temperature range 163–613 K. At low temperatures (163–300 K) the ratio is 2.2 exp (1180/RT). The pre-exponential factor of 2.2 agree
Publikováno v:
Reaction Kinetics and Catalysis Letters. 7:321-326
The rate constants for Br(2P1/2) and Br(2P3/2) atoms in the reaction Br+CH3F→HBr+CH2F in photobromination of CH3F have been determined. Their ratio is 10−(2.6±0.5) exp(10100±1000/RT) in the temperature range of 60–200 °C.
Publikováno v:
Chemical Physics. 97:449-455
The spatial separation of nuclear spin modifications of CH3F by the light-induced drift (LID) effect has been investigated. The separations occurs
Publikováno v:
Reaction Kinetics and Catalysis Letters. 29:9-14
From mass-spectrometric data, it has been established that the main gaseous product of silane oxidation by oxygen at low pressures is molecular hydrogen. Isotopic analysis of the hydrogen formed in the oxidation of SiH4+SiD4 mixtures indicates that n
Publikováno v:
Optics Communications. 40:129-134
The light-induced drift (LID) of CH 3 F molecules under vibrational excitation by a cw CO 2 laser has been investigated experimentally. The frequency dependence of the LID effect has been studied. The characteristic feature of this dependence (the ef
Publikováno v:
Reaction Kinetics and Catalysis Letters. 3:131-137
At 148–298 K, the rate constant for the reaction of methane molecules excited into bending vibration with atomic chlorine does not exceed by more than 30 times the corresponding constant for methane in thermal equilibrium. Consequently, at low temp