Zobrazeno 1 - 10
of 49
pro vyhledávání: '"V. N. Boiko"'
Publikováno v:
Journal of Fluorine Chemistry. 143:123-129
Reactions of 2,4,6-tris(fluorosulfonyl)chlorobenzene 1 with O-, N-, S-, C-nucleophiles and F-anion showed high reactivity of 1 that was defined by three strong electron withdrawing SO2F groups creating several electrophilic centers within the molecul
Autor:
V. N. Boiko
Publikováno v:
Beilstein Journal of Organic Chemistry
Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, Pp 880-921 (2010)
Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, Pp 880-921 (2010)
This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutic
Autor:
V. N. Boiko, Oksana M. Kamoshenkova
Publikováno v:
Journal of Fluorine Chemistry. 131:248-253
The reactions of 1,3,5-tris(fluorosulfonyl)benzene 1 with nucleophilic agents were investigated. It was found that morpholine, β,β,β-trifluoroethanol in the presence of triethylamine and sodium azide formed corresponding 1,3,5-trisulfonyl derivati
Publikováno v:
Tetrahedron Letters. 49:2719-2721
We have found that symmetrical benzene trisulfonic-acid trifluoride 1 is able to undergo nucleophilic addition at free positions on the aromatic ring. Its reactions with sodium sulfite, morpholine and carbanions of malonic and acetoacetic esters, dim
Autor:
Wieland Tyrra, Yurii L. Yagupolskii, Andrey A. Filatov, Ingo Pantenburg, Dieter Naumann, Hendrik T. M. Fischer, Frank Schulz, V. N. Boiko
Publikováno v:
ChemInform. 43
Convenient procedures for the synthesis of the title compounds and for the preparation of a variety of 2,4,6-tris(fluorosulfonyl)phenolates are presented.
Autor:
V. N. Boiko, G. M. Shchupak
Publikováno v:
Journal of Fluorine Chemistry. 69:207-212
Perfluoroalkylation of aliphatic, aromatic and heterocyclic thiols by perfluoroalkyl iodides in the presence of Et 3N appears to occur spontaneously under daylight or the usual laboratory lighting conditions at 20–22 °C and is complete in 10–15
The activation of SNAr reactions by the superstrong electron-withdrawing substituent CF3S(O)=NSO2CF3
Publikováno v:
Journal of Fluorine Chemistry. 67:119-123
The chlorine lability of the 2-nitrochlorobenzene derivative which contains the superstrong electron-withdrawing substituent CF 3 S(O)=NSO 2 CF 3 in position 4 has been compared with the analogous 4-trifluoromethylsulphonylderivative and picryl chlor
Autor:
V. N. Boiko, I. A. Onopa
Publikováno v:
Soil Mechanics and Foundation Engineering. 30:162-165
It is suggested that the bed coefficient be considered as a characteristic of the contact interaction of rigid pavement and the soil base. Equations are derived for the relationship between the bed coefficient and the modulus of elasticity of the soi
Autor:
V. N. Boiko
Publikováno v:
ChemInform. 41
This review covers all of the common methods for the syntheses of aromatic and heterocyclic perfluoroalkyl sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutic
Autor:
G. M. Shchupak, V. N. Boiko
Publikováno v:
ChemInform. 26
Perfluoroalkylation of aliphatic, aromatic and heterocyclic thiols by perfluoroalkyl iodides in the presence of Et 3N appears to occur spontaneously under daylight or the usual laboratory lighting conditions at 20–22 °C and is complete in 10–15