Zobrazeno 1 - 10
of 15
pro vyhledávání: '"V. M. Smolyakov"'
Autor:
D. Yu. Nilov, V. M. Smolyakov
Publikováno v:
Russian Journal of Physical Chemistry A. 90:1702-1705
A fourteen-constant graphic scheme is proposed for evaluating the thermodynamic properties of branched paraffin hydrocarbons. Absolute entropy Sf, 298 gas of 159 alkanes, of which 157 alkanes have yet to be studied experimentally, are calculated usin
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dbabac50a945d786f7d80ca29e4b4782
https://doi.org/10.1134/s0036024416080203
https://doi.org/10.1134/s0036024416080203
Autor:
V. M. Smolyakov, V. V. Grebeshkov
Publikováno v:
Russian Journal of Physical Chemistry A. 89:914-918
A ten-constant additive model is obtained for calculating the physicochemical properties of a number of C n H2n−2 alkynes, based on the group additivity method (with allowance for the initial atomic environment), two topological indices that allow
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f4df239cc37023348f0a161167a0e624
https://doi.org/10.1134/s0036024415050295
https://doi.org/10.1134/s0036024415050295
Autor:
V. M. Smolyakov, D. Yu. Nilov
Publikováno v:
Russian Journal of Physical Chemistry A. 89:159-167
Using Polya’s theorem, cycle indices are derived that identify the chiral and achiral substitution isomers of an allene (1,2-propadiene). Equations of symmetry that allow us to determine the number of isomers in a series and arrange the isomers acc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0b4b8899a69423e1dc01048b9a346b33
https://doi.org/10.1134/s003602441502017x
https://doi.org/10.1134/s003602441502017x
Publikováno v:
Russian Journal of Physical Chemistry A. 87:1180-1185
An additive scheme with 11 constants is derived from the coefficients of characteristic polynomials (CCPs) of adjacency matrix A of irregular molecular graphs (IMG) for molecules that contain a bivalent heteroatom -SH or -OH at the beginning of the c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a0b5733232a8b89ccd3cb55629cdc3bb
https://doi.org/10.1134/s0036024413070297
https://doi.org/10.1134/s0036024413070297
Autor:
V. M. Smolyakov, D. Yu. Nilov
Publikováno v:
Russian Journal of Physical Chemistry A. 87:516-520
A 18-constant additive scheme for calculating the physicochemical properties of alkylsilanes is obtained, based on the transferability of subgraphs in molecular graphs of the homologic SiC n H2n + 4 series of alkylsilanes. The model considers multipl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c404ddac24a7316280f9611c06c006f0
https://doi.org/10.1134/s0036024413030199
https://doi.org/10.1134/s0036024413030199
Publikováno v:
Journal of Structural Chemistry. 54:50-58
Combinatorial analysis methods are employed to solve the problem of determining the number and form of X-substituted (X, XY, … are some substituents) of carbometallic derivatives of boranes (C5H5)Co(C2B9H11) C1v and (C5H5)Co(C5B6H11) C5v (over vert
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b66c6cdd8b28f21acad8acb8ff871fec
https://doi.org/10.1134/s0022476613010071
https://doi.org/10.1134/s0022476613010071
Autor:
V. M. Smolyakov, D. Yu. Nilov
Publikováno v:
Journal of Structural Chemistry. 53:1024-1030
Based on the similarity of subgraphs in the molecular graphs of a homological series of SiH4-SiC8H20 alkylsilanes a 22-constant additive scheme is obtained for the calculation of their physicochemical properties. By the example of SiH4-SiC8H20 alkyls
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c6cfd1c910ad127b544b1798cbfac8f7
https://doi.org/10.1134/s0022476612060029
https://doi.org/10.1134/s0022476612060029
Autor:
V. V. Grebeshkov, V. M. Smolyakov
Publikováno v:
Russian Journal of Physical Chemistry A. 86:736-740
A 16-constant additive scheme was derived for calculating the physicochemical properties of saturated monoalcohols CH4O-C9H20O and decomposing the triangular numbers of the Pascal triangle based on the similarity of subgraphs in the molecular graphs
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5c165b67907fa744b8a9fdaf8dbd3eff
https://doi.org/10.1134/s0036024412050123
https://doi.org/10.1134/s0036024412050123
Autor:
D. Yu. Nilov, V. M. Smolyakov
Publikováno v:
Russian Journal of Physical Chemistry A. 86:729-735
A method for the construction of additive models for calculations of the properties of substitution isomers of basis structures is described for the example of a series of X-substituted methylsilanes CH3 − k X k -SiH3 − l X l (where X = CH3, F, C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0abd4f521e214c3c0dcc09acdda9c203
https://doi.org/10.1134/s0036024412050275
https://doi.org/10.1134/s0036024412050275
Publikováno v:
Russian Journal of Physical Chemistry A. 86:257-263
The problem of determining the number and type of X-substituted (where X represents certain substituents) carbometallic derivatives of hydroborons [Co(C2B9H11)2]−C2h and [Co(C5B6H11)2]−D5d (from apexes) was solved on the basis of G. Polya’s the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0824fa231c8a65613d368a4702b071dc
https://doi.org/10.1134/s0036024412020276
https://doi.org/10.1134/s0036024412020276