Zobrazeno 1 - 10
of 12
pro vyhledávání: '"V. L. Survilo"'
Publikováno v:
Chemistry of Natural Compounds. 46:750-755
New derivatives of steroidal 6-ketoximes containing α-chloropyridine neonicotinoid groups characteristic of bioactive compounds were synthesized by formation of oximes of cholestane and stigmastane 3β,5-dihydroxy-6-ketosteroids with O-(2-chloropyri
Publikováno v:
Chemistry of Natural Compounds. 45:200-204
New esters of 3β,5α,6β-trihydroxysteroids and 3β,5-dihydroxy-6-ketosteroids containing 6-chloropyridine groups characteristic of the alkaloid epibatidine were synthesized by acylation with 6-chloronicotinoylchloride.
Publikováno v:
Chemistry of Natural Compounds. 45:205-208
New steroid derivatives containing 6-chloropyridine groups characteristic of the alkaloid epibatidine and neonicotinoid insecticides were synthesized by reacting 3β,5α,6β-trihydroxysteroids or 3β,5-dihydroxy-6ketosteroids with 2-chloro-5-chlorome
Publikováno v:
Chemistry of Natural Compounds. 39:411-437
Literature data published in 1998-2002 on the chemical synthesis of ecdysteroids and their structural analogs were reviewed.
Autor:
V. L. Survilo, N. V. Kovganko
Publikováno v:
Chemistry of Natural Compounds. 38:340-343
22,25-Dideoxyecdysone (1) and 5α-22,25-dideoxyecdysone (1a) were prepared from cholesterol via a new scheme using the key intermediates 3β-chloro-5α-bromo-6-ketone 3, 3β-chloro-7α-bromo-6-ketone 4, and 2,7-dien-6-one 7.
Autor:
N. V. Kovganko, V. L. Survilo
Publikováno v:
Chemistry of Natural Compounds. 38:257-263
3β-Chloro-5α,7α-dibromo-6-ketosteroids 5a and 5b are synthesized from β-sitosterol (1a) and cholesterol (1b). Dehydrohalogenation of these forms 7α-bromo-2,4-dien-6-ones (6a-b), 2,4-dien-6-ones (7a-b), and 14α-hydroperoxy-2,4,7-trien-6-ones (8a
Publikováno v:
Chemistry of Natural Compounds. 38:443-446
Steroids 1-16, which are intermediates in the synthesis of ecdysteroids, have been shown to possess insecticidal activity for larvae of the Colorado beetle Leptinotarsa decemlineata. Active growth- and development-regulators were found among them.
Publikováno v:
Chemistry of Natural Compounds. 38:439-442
Structural analogs of ecdysteroids were screened for insecticidal activity for larvae of the Colorado beetle Leptinotarsa decemlineata using a contact-feed method. High activity was found for compounds 3, 6b, 7a, and 9a.
Publikováno v:
Chemistry of Natural Compounds. 37:343-346
13 C NMR spectra have been studied and signals of C atoms have been assigned for 5- and 7-bromo-6-ketosteroids, which are intermediates in the synthesis of ecdysteroids.
Autor:
V. L. Survilo, N. V. Kovganko
Publikováno v:
Chemistry of Natural Compounds. 37:154-161
A new synthetic scheme has been developed to synthesize 22,23-epoxyecdysteroids from stigmasterol