Zobrazeno 1 - 10
of 75
pro vyhledávání: '"V. G. Rozinov"'
Publikováno v:
Russian Chemical Bulletin. 64:732-737
The reactions of trichloro(2-ethoxyethenyl)phosphonium and trichloro(styryl)phosphonium hexachlorophosphorates with triethylamine were studied by 1H, 13C, and 31P NMR spectroscopy. It was shown that phosphonyl chlorides are the primary products of th
Publikováno v:
Russian Journal of General Chemistry. 86:512-514
C-Phosphorylation of a number of unsaturated ketones with phosphorus pentachloride has been studied. Structure of the obtained dienyltrichlorophosphonium hexachlorophosphorates was established by means of 1H, 13C, and 31P NMR spectroscopy.
Phosphorus-containing dienes derived from diacetone alcohol: synthesis and study by NMR spectroscopy
Publikováno v:
Russian Chemical Bulletin. 64:2744-2746
C-Phosphorylation of diacetone alcohol with phosphorus pentachloride was studied. The products, pentadienyltrichlorophosphonium hexachlorophosphates and (4-chloro-2-methylpenta-1, 3-dien-1-yl)phosphonyl and (2-chloro-4-methylpenta-1, 3-dien-1-yl)phos
Publikováno v:
Russian Chemical Bulletin. 62:39-46
Phosphorylation of tertiary amines containing at least two ethyl groups at the nitrogen atom with phosphorus pentachloride was studied. New C-chlorophosphorylated enamines were characterized by NMR spectroscopy. A scheme was suggested for the phospho
Publikováno v:
Russian Journal of Organic Chemistry. 48:676-681
The stereochemical structure of unsaturated phosphonic acids dichlorides containing fragments C=C-POCl2 and C=N-POCl2 was investigated by 31P NMR spectroscopy and quantum chemistry. Starting from the experimental measurement and theoretical calculati
Publikováno v:
Russian Journal of General Chemistry. 82:72-76
The study by 1H and 31P NMR spectroscopy has shown that phosphorylation of N,N-dimethylurea and diethylcyanamide with phosphorus pentachloride results in the formation of N′-(N,N-dialkylchloroformamidino) trichlorophosphonium hexachlorophosphorates
Publikováno v:
Russian Journal of Organic Chemistry. 47:1859-1864
Theoretical and experimental studies on magnetic shielding of the phosphorus nucleus in trichloro-[2-(1H-pyrazol-1-yl)ethenyl]phosphonium hexachlorophosphate(V) and 1,1,1,1-tetrachloro-1H-1λ6-pyrazolo-[1,2-a][1,2,3]diazaphosphol-8-ium-1-ide showed t
Publikováno v:
Russian Journal of Organic Chemistry. 47:1865-1869
Intermolecular coordination effects on the 31P NMR spectra of molecular complexes of N-vinylimidazole and 1-allyl-3,5-dimethylpyrazole with phosphorus pentachloride were studied by theoretical and experimental methods. The formation of intermolecular
Publikováno v:
Magnetic Resonance in Chemistry. 47:149-157
The structure of novel phosphorus-containing N-vinylazoles prepared by action of phosphorus pentachloride has been studied by multinuclear 1H, 13C, 15N, 31P and two-dimensional (2D) NMR spectroscopy. N-vinyl-substituted 1,2-diazoles and 1,2,3-triazol
Publikováno v:
Russian Journal of Organic Chemistry. 49:195-197
Relying on the study of the electronic structure of [dimethylamino(chloro)methylideneamino] trichlorophosphonium hexachlorophosphate by means of 31P NMR and quantum chemistry it was shown that in chloroform this substance existed as trichlorophosphaz