Zobrazeno 1 - 10
of 17
pro vyhledávání: '"V. G. Pastushchak"'
Publikováno v:
Radiochemistry. 48:348-351
The rate of Pu(IV) reduction with tert-butylhydrazine in an HNO3 solution is described by the equation-d[Pu(IV)]/dt = k[Pu(IV)]2[(CH3)3CN2H4+]/[H+], where k = 69.4 ⊥ 3.0 l mol−1 min−1 at 50°C. The activation energy is E = 122 ⊥ 4 kJ mol−1.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8700b0bb1ee65fc00ad7d250d551b725
https://doi.org/10.1134/s1066362206040060
https://doi.org/10.1134/s1066362206040060
Publikováno v:
Radiochemistry. 47:69-73
Reduction of Pu(VI) to Pu(III) with acetaldoxime (CH3CHNOH) in an HNO3 solution involves three consecutive steps Pu(VI) → Pu(V) → Pu(IV) → Pu(III), and also reproportionation of Pu(IV). Complete kinetics equations of these steps were derived an
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8342cebe802158ebc70a6e0bcc2f3332
https://doi.org/10.1007/s11137-005-0050-5
https://doi.org/10.1007/s11137-005-0050-5
Publikováno v:
Radiochemistry. 46:125-130
Reduction of Pu(VI) to Pu(III) with hydroxyethylhydrazine (HOC2H4N2H3) in HNO3 solutions involves the following consecutive steps2: Pu(VI) + HOC2H4N2H4 → Pu(V) + ...; Pu(V) + HOC2H4N2H4+ → Pu(IV) + ...; Pu(V) + Pu(III) → 2Pu(IV); and Pu(IV) + H
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::764a16477c65f0f195eb207dbe0380c0
https://doi.org/10.1023/b:rach.0000024936.87231.c0
https://doi.org/10.1023/b:rach.0000024936.87231.c0
Publikováno v:
Radiochemistry. 44:541-545
3,3'-Bis(diaziridinyl), H2N2C2H2N2H2, is oxidized with Pu(IV) ions in excess of reductant to bis(diazirinyl), N2C2H2N2, and in excess of oxidant, to nitrogen and acetic acid. The reaction rate in the HNO3 solution at a constant ionic strength is desc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7f2bb961038e6f1ed685c601a9c021c1
https://doi.org/10.1023/a:1022372124550
https://doi.org/10.1023/a:1022372124550
Autor:
Shaw, Thomas E., Jones, Zachary R., Adelman, Sara L., Anderson, Nickolas H., Bowes, Eric G., Bauer, Eric D., Dan, David, Klouda, Jan, Knope, Karah E., Kozimor, Stosh A., MacInnes, Molly M., Mocko, Veronika, Rocha, Francisca R., Root, Harrison D., Stein, Benjamin W., Thompsona, Joe D., Wacker, Jennifer N.
Publikováno v:
Chemical Science; 8/28/2024, Vol. 15 Issue 32, p12754-12764, 11p
Publikováno v:
Journal of Radioanalytical & Nuclear Chemistry. Feb2009, Vol. 279 Issue 2, p423-429. 7p. 1 Diagram, 1 Chart, 4 Graphs.
Publikováno v:
Radiochemistry. Jul2006, Vol. 48 Issue 4, p348-351. 4p. 1 Chart.
Publikováno v:
Radiochemistry. Jan2005, Vol. 47 Issue 1, p69-73. 5p.
Publikováno v:
Radiochemistry. Mar/Apr2004, Vol. 46 Issue 2, p125-130. 6p.
Autor:
Davies, Michael B.
Publikováno v:
Annual Reports on the Progress of Chemistry: Section A; 2005, Vol. 101, p548-584, 37p