Zobrazeno 1 - 10
of 38
pro vyhledávání: '"V. F. Sizoi"'
Publikováno v:
Journal of Organometallic Chemistry. 94:425-440
Mass spectra of η 5 -RC 5 H 4 Re(CO) 3 , where R H, CH 3 , I, CH 2 OH, CHO, COOH, CN, COCH 3 , COOCH 3 , CH 2 Cl, CHNC 6 H 5 , C(OH)(CH 3 ) 2 or C(OH)-(C 6 H 5 ) 2 , have been studied. The routes of fragmentation of the complexes under electr
Autor:
D. V. Zagorevskii, A. N. Nesmeyanov, A.M. Baran, E.I. Klimova, V. F. Sizoi, Yu. S. Nekrasov, V.M. Postnov
Publikováno v:
Journal of Organometallic Chemistry. 169:77-81
The main processes of the electron-impact induced fragmentation of the ferrocenyl and cymantrenyl analogues of chalcones RCOCH=CHR′ (R, R′ = C5H4FeC5H5, C5H4Mn(CO)3, or aryl) involve a cleavage of the metalligand bond. A “chalcone” mode of
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 37:1039-1042
The regioselective arylation of unsaturated compounds was carried out under metal complex and phase transfer conditions by the action of aryl iodides.
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:1239-1243
1. Previously unknown derivatives of cymantrene and its rhenium analog [(η5-C5H5)M(CO)2(PhNO)] (M = Mn, Re) with nitrosobenzene as two-electron ligand, and also nitrosobenzene derivatives of group VI B metal carbonyl, were obtained and characterized
Publikováno v:
Journal of Organometallic Chemistry. 97:203-212
The mass spectrometry behaviour of dimethylaminomethyl- and α-(dimethylamino)ethyl derivatives of cymantrene and ferrocene, their iodine methylates as well as of the deutero analogues of these compounds has been studied. It has been shown that mass
Publikováno v:
Chemistry of Heterocyclic Compounds. 19:1072-1075
Allyl hetaryl Sulfides with an allyl fragment that is part of a heteroaromatic ring undergo a [3,3]-sigmatropic rearrangement when they are heated in various solvents, as a result of which uncondensed binuclear heterocyclic compounds are formed. On t
Autor:
N. E. Kolobova, V. G. Andrianov, V. F. Sizoi, Igor T. Chizhevsky, N. V. Rastova, Pavel V. Petrovskii, Yu. T. Struchkov
Publikováno v:
Journal of Organometallic Chemistry. 262:81-84
The cationic alkoxyallylolefin complexes of rhodium, [Rh(η 2 -5,6-η 3 -2,3,8-C 7 H 7 -2-CHOR)(η 5 -C 5 H 5 )] + An − (II) were prepared as stable salts from the reaction of Rh(η 4 -C 7 H 7 -2-CHO)(η 5 -C 5 H 5 ) (I) with ROH (R = Me, Et) in th
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:443-446
1. For nonclassical ions of the type of C5H5E+ (E=C, Si), the CNDO/2 method predicts a higher stability for the structures of charged nido-clusters than for classical structures of the phenyl cation type. 2. For the ions C3H3E+ (E=C, Si), the most fa
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 35:1702-1707
1. By means of the18O-labeled compounds it was established that the alkoxyallylolefin complexes of rhodium [Rh(η2-5,6-η3-2,3,8-C7H7-2-CH\(\dddot ---\)OR)(η5-C5H5)]+ An− (R = Alk) formed in the O-alkylation of (2-formylnorbornadiene) cyclopentadi
Publikováno v:
Journal of Organometallic Chemistry. 252:201-204
The cyclopentadienyl ligands in Cp(CO)2FePh, Cp(CO)2FeCH2Ph and [Cp(CO)2Fe]2 were metalated by BuLi in THF at −78°C. With Cp(CO)2FePh it was possible to employ the reaction for the synthesis of cyclopentadienyl carbonyl complexes substituted on th