Zobrazeno 1 - 10
of 85
pro vyhledávání: '"V. D. Tyurin"'
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:674-680
Thermal decomposition of the [FeCp(SPh)CO]2 complex and its reaction with the surface of activated silica gel were investigated by Mossbauer spectroscopy. A small amount of a complex with properties similar to ferrocene is separated in the first stag
Autor:
G. G. Aleksandrov, A. I. Nekhaev, M. Mavlonov, N. S. Nametkin, V. G. Andrianov, O. V. Kuz'min, V. D. Tyurin, Yu. T. Struchkov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 28:1266-1271
1. Derivatives of dithiodiironhexacarbonyl containing Si and Ge are synthesized. 2. Upon reaction of the etherate of HGeCl3 with dithiodiironhexacarbonyl, the introduction of a GeCl2 fragment at the S-S bond occurs; upon utilization of aminates of HG
Autor:
V. D. Tyurin, G. G. Aleksandrov, I. V. Petrosyan, B. I. Kolobkov, Yu. T. Struchkov, N. S. Nametkin, A. M. Krapivin
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 30:2133-2138
1. Dithiolane diiron hexacarbonyl complexes are formed in the reaction of S8 with Fe3(CO)12 in the presence of cyclohexene or 1-hexene. When cyclohexene is used, sulfur atoms are incorporated at the double bond to give cyclic polysulfides. 2. The str
Publikováno v:
Journal of Organometallic Chemistry. 254:339-344
The electron impact mass spectra of diironhexacarbonyl complexes prepared from benzylidene- and α-naphthylidene-anilines, benzalazine and ketazines of acetophenone, p -bromoacetophenone and benzophenone are studied. The main fragmentation of the lig
Publikováno v:
Journal of Organometallic Chemistry. 149:355-370
Synthesis of S 2 Fe 2 (CO) 6 and S 2 Fe 3 (CO) 9 by direct substitution of the carbonyl ligands in iron carbonyls with sulfur is described. The relative reactivities were determined for both iron carbonyls and organosulfur compounds in reactions of R
Autor:
O. V. Kuz'min, V. D. Tyurin, N.A. Kubasova, N. V. Alekseev, E. A. Chernyshev, M. G. Los, Vladimir G. Zaikin, N. S. Nametkin, A. I. Gusev, A.V. Lebedev, A.M. Krapivin
Publikováno v:
Journal of Organometallic Chemistry. 252:143-148
Reaction of trimethylvinylsilane with S 8 in the presence of Fe 3 (CO) 12 led to 1-trimethylsilyl-μ- S , S′ -ethylenedithiolatohexacarbonyldiiron and 1-methyl-3-trimethylsilyl-2,5-dithiacyclopentane. An X-ray study was carried out on compound VI.
Autor:
N. G. Komalenkova, N. I. Kirillova, O. V. Kuz'min, A. I. Gusev, N. S. Nametkin, V. D. Tyurin, E. A. Chernyshev, A. V. Lebedev
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:585-588
1. Sulfur atoms are inserted into the olefinic double bond in the reaction of S8 with 1, 1-dimethylsila-3-cyclopentene in the presence of Fe3(CO)12 to form cyclic and crosslinked polysulfides as well as a diironhexacarbonyl dithiolane complex. 2. An
Autor:
O. V. Kuz'min, A. V. Lebedev, E. A. Chernyshev, V. D. Tyurin, N. S. Nametkin, A. I. Nekhaev, B. K. Kabanov
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 33:2184-2187
1. The thermal decomposition of 1-trimethylsilyl-μ3-S,S-ethylenedithiolatohexacarbonyldiiron leading to the formation of trimethylvinylsilane, CO and FeS is accompanied by partial desilylation with the formation of ethylene and propylene. 2. The pyr
Publikováno v:
Journal of Organometallic Chemistry. 302:243-248
The precipitate formed by the reaction of benzalazine with Fe3(CO)12 yields the triangular clusters Fe3(PhCH2N)(CO)10 and HFe3(PhCHN)(CO)9 when decomposed by concentrated hydrochloric and phosphorous acids, respectively. The structure of μ-(o-C6H
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 31:617-620
1. The thermogravimetric method was used to study the thermal stability of some diiron hexacarbonyl complexes that were obtained from aromatic azines. The incipient decomposition temperatures of the complexes, which contain two three-electron nitroge