Zobrazeno 1 - 10
of 23
pro vyhledávání: '"V Ia, Chirva"'
Publikováno v:
Bioorganicheskaia khimiia. 37(5)
The catalytic phase transfer reactions of 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-a-D-glucopyranosyl chloride with thiosubstituted 4-phenyl-5-R-thio-Delta2-1,2,4-triazolin-3-ones in solid alkali-organic solvent and in aqueous alkali-organic solvent we
Publikováno v:
Bioorganicheskaia khimiia. 37(2)
In the phase transfer system solid calcium carbonate-acetonitrile, per acetate alpha-D-glucosaminilchloride glycosilate easily deprotoned isatine-3-oximes hydroxyl groups. It was found that the presence in the reaction mixture a catalytic amounts of
Publikováno v:
Bioorganicheskaia khimiia. 34(6)
Regioselective N-beta-glucosamination of various unsubstituted or C4-, C5-, or C6-monosubstituted indolin-2-ones under phase transfer conditions was studied. The regioselectivity was unambiguously proved by (1)H NMR spectroscopy and X-ray analysis. T
Autor:
N M, Zholobak, N Ia, Spivak, A E, Zemliakov, V V, Tsikalov, T A, Chupakhina, V O, Kur'ianov, V Ia, Chirva
Publikováno v:
Mikrobiolohichnyi zhurnal (Kiev, Ukraine : 1993). 69(4)
The uninvestigated interferon (IFN)-inducing capacity of glycoside derivatives of N-acetylmuramoyl-L-alanyl-D-isoglutamine (MDP) has been studied. Most MDP glycosides tested in vitro were more active than the reference preparation MDP. Under the in v
Autor:
V O, Kur'ianov, T A, Chupakhina, A E, Zemliakov, V Ia, Chirva, O V, Shishkin, S V, Shishkina, S A, Kotliar, G L, Kamalov
Publikováno v:
Bioorganicheskaia khimiia. 32(6)
Glycosylation of methylbenzoxazolone-2 and benzothiazolone-2 with the full acetate of alpha-D-glucosaminyl chloride in the phase transfer systems investigated (solid-organic solvent and aqueous alkali-organic solvent) regioselectively leads to the co
Publikováno v:
Bioorganicheskaia khimiia. 32(5)
5-Phenyl-1,3,4-oxadiazole-2-thiol is glycosylated easily and in high yields with 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-alpha-D-glucopyranosyl chloride in the presence of catalytic amounts of aliphatic and aromatic crown ethers under phase transfer (
Publikováno v:
Bioorganicheskaia khimiia. 32(4)
Anomeric pairs of alpha- and beta-dodecyl, alpha- and beta-(1-pentylhexyl), and alpha- and beta-cyclododecyl glycosides of N-acetylmuramyl-L-alanyl-D-isoglutamine (MDP) were synthesized. The starting beta-D-glucosaminides were obtained by the oxazoli
Publikováno v:
Bioorganicheskaia khimiia. 31(6)
The following glycosides of N-acetylmuramyl-L-alanyl-D-isoglutamine (MDP) were synthesized: beta-4-tert-butylcyclohexyl MDP, beta-2-(adamant-1-yl)ethyl MDP, beta-2,2-diphenylethyl MDP, and 3-2-(p-biphenyl)ethyl MDP. The starting peracetylated beta-N-
Autor:
V O, Kur'ianov, T A, Chupakhina, A E, Zemliakov, V Ia, Chirva, O V, Shishkin, S V, Shishkina, S A, Kotliar, G L, Kamalov
Publikováno v:
Bioorganicheskaia khimiia. 31(5)
The use of crown ethers for a phase transfer-catalyzed synthesis of heteroaromatic glycosides of N-acetylglucosamine was studied. The solid-liquid system and the catalysis by 15-crown-5 were found to provide for both a 100% conversion of the alpha-D-
Publikováno v:
Bioorganicheskaia khimiia. 31(3)
Glycosylation of phenols with alpha-D-glucosaminyl chloride peracetate catalyzed by polyethylene glycol (PEG) was carried out in a solid-liquid phase transfer system at room temperature. The results were compared with those previously obtained for th