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pro vyhledávání: '"V E, Goswami"'
Autor:
Max C. Holthausen, Adam Walli, Serhiy Demeshko, V. E. Goswami, Moritz Förster, Sebastian Dechert, Franc Meyer
Publikováno v:
Chemical Science. 8:3031-3037
CuII2(μ-η2:η2-peroxido) and CuIII2(μ-oxido)2 cores represent key intermediates in copper/dioxygen chemistry, and they are mechanistically important for biological hydroxylation and oxidation reactions mediated by dinuclear (type III) copper metal
Publikováno v:
Chemical Science
Key peroxido and bis(μ-oxido) Cu2/O2 intermediates can be interconverted by peripheral (de)protonation events on the ligand backbone.
CuII2(μ-η2:η2-peroxido) and CuIII2(μ-oxido)2 cores represent key intermediates in copper/dioxygen chemistr
CuII2(μ-η2:η2-peroxido) and CuIII2(μ-oxido)2 cores represent key intermediates in copper/dioxygen chemistr