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of 10
pro vyhledávání: '"Uwe Stelzer"'
Publikováno v:
Tetrahedron: Asymmetry. 9:1043-1049
A technical scale preparation of optically active (1 R , cis ,α S )-cypermethrine 4 from racemic m -phenoxybenzaldehyde cyanohydrin acetate ( RS )- 1 and (1 R , cis )-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid chloride (1 R , cis
Publikováno v:
Tetrahedron: Asymmetry. 7:607-618
(S)-2- Azidonitriles (S)- 4 are easily accessible from (R)-2- (sulfonyloxy)nitriles (R)- 2 by nucleophilic substitution with alkali azides 3 under complete inversion of configuration. The azidonitriles (S)- 4 can be converted by catalytic hydrogenati
Autor:
Uwe Stelzer, Franz Effenberger
Publikováno v:
Tetrahedron: Asymmetry. 6:283-286
2-Monosubstituted (S)-aziridines (S)- 3 were obtained by hydrogenation of (R)-2-sulfonyloxynitriles (R)- 2 with LiAlH4 in good chemical yields and high enantiomeric excess.
Publikováno v:
Liebigs Annalen der Chemie. 1993:1303-1311
Amino Acids, 17. – A New Synthesis of Didehydro Dipeptides and Didehydro Tripeptides Esters of N-phthaloyl-protected (R)- or (S)-didehydro dipeptides 5–7 were obtained in good yields by the perrhenate-catalyzed decomposition of 2-azidocarboxylate
Autor:
Franz Effenberger, Uwe Stelzer
Publikováno v:
Chemische Berichte. 126:779-786
Enzyme-Catalyzed Reactions, 15[1]. – Preparation of (R)1-2-(Sulfonyloxy)nitriles and Their Reactions with Acetates – Inversion of the Configuration of Optically Active Cyanohydrins 2-(Sulfonyloxy)nitriles (R)-6, 7, 8 are obtained in high optical
Autor:
Uwe Stelzer, Franz Effenberger
Publikováno v:
Tetrahedron: Asymmetry. 4:161-164
(S)-2-fluoronitriles (S)-4 are obtained in good chemical and high optical yields from (R)-cyanohydrins (R)-2 or (R)-cyanohydrin trimethylsilylethers (R)-3 by fluorination with DAST or by nucleophilic substitution of α-sulfonyloxynitriles (R)-6,7 wit
Publikováno v:
ChemInform. 25
Publikováno v:
ChemInform. 27
Autor:
Franz Effenberger, Uwe Stelzer
We report here on an important extension of the synthetic potential of optically active cyanohydrins by conversion of the hydroxy group into a good leaving group. Of particular interest are reactions of the cyanohydrin derivatives in which the nitrog
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1aa2ebf6ca5cae202ed31c7fd74cb94d
Autor:
Franz Effenberger, Uwe Stelzer
Publikováno v:
Angewandte Chemie. 103:866-867
Hier berichten wir über eine wichtige Erweiterung des Synthesepotentials optisch aktiver Cyanhydrine durch Uberfiührung der Hydroxygruppe in eine gute Austrittsgruppe. Besonderes Interesse kommt dabei den Reaktionen der Cyanhydrinderivate zu, bei d