Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Urs D. Lengweiler"'
Publikováno v:
Proceedings of the National Academy of Sciences. 94:9075-9079
Traditionally, the structure and properties of natural products have been determined by total synthesis and comparison with authentic samples. We have now applied this procedure to the first nonproteinaceous ion channel, isolated from bacterial plasm
Publikováno v:
Helvetica Chimica Acta. 80:989-1026
As previously shown, oligo- and poly(β-hydroxyalkanoates) have a high tendency to form lamellar crystallites with ca. 50-A thickness which corresponds to chain lengths of 16 units (Fig. 1). To have monodisperse model compounds, we have now prepared
Publikováno v:
Angewandte Chemie. 108:2969-2972
Publikováno v:
Helvetica Chimica Acta. 79:670-701
Monodisperse Linear and Cyclic Oligo[(R)-3-hydroxybutanoates] Containing up to 128 Monomeric Units Using benzyl ester/(tert-butyl)diphenylsilyl ether protection, (COCl)2/pyridine esterification conditions, and a fragment-coupling strategy (with H2/Pd
Autor:
Kathy Sykes, Hans-Martin Müller, Terence J McMaster, Dieter Seebach, Phil Barker, Peter J. Barham, Mervyn J Miles, Urs D. Lengweiler
Publikováno v:
Journal of Materials Science. 30:623-627
Attempts have been made to image the fold surface of a single crystal of polyhydroxybutyrate (PHB) using the relatively new technique of atomic force microscopy (AFM). To overcome the obscuring of the fold surface by loose loops of polymer and chain
Publikováno v:
Helvetica Chimica Acta. 77:2007-2034
Cyclic oligomers of (R)-3-hydroxyvaleric acid (3-HV) are prepared from the monomer by three different methods, giving various ratios of the oligomers. The macrocycles containing three to twelve 3-HV units (12- to 48-membered rings) are isolated in pu
Autor:
Hans-Martin Müller, Urs D. Lengweiler, Peter J. Barham, Phil Barker, Albert K. Beck, H. Michael Bürger, Dieter Seebach, Kathy Sykes
Publikováno v:
Helvetica Chimica Acta. 77:1099-1123
Repetitive treatment of the biopolymer P(3-HB) (molecular weight > 105 Dalton, storage or s-P(3-HB)), with lithium hexamethyl disilazanid (LHMDS) at −70° in THF leads to a mixture of oligomers with increasingly sharp distribution around a 15-, 30-
Publikováno v:
ChemInform. 28
As previously shown, oligo- and poly(β-hydroxyalkanoates) have a high tendency to form lamellar crystallites with ca. 50-A thickness which corresponds to chain lengths of 16 units (Fig. 1). To have monodisperse model compounds, we have now prepared
Publikováno v:
Helvetica Chimica Acta. 75:438-441
The use of α,α,α′,α′ -tetraaryl-1,3-dioxolane-4,5-dimethanols ( = TADDOLs;1) as chiral NMR shift reagents (1H, 13C, 19F) is described. In many cases, the ratio of enantiomeric alcohols and amines can be determined under standard conditions of
Publikováno v:
Angewandte Chemie International Edition in English. 35:2795-2797