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Solvent-mediated charge separation drives alternative hydrogenation path of furanics in liquid water
Autor:
Zheng Zhao, Yaping Li, Sanwu Wang, Wenhua Xue, Dieu-Thy Nguyen, Nicholas M. Briggs, Reda M. Bababrik, Daniel E. Resasco, Steven P. Crossley, Bin Wang, Umi Nguyen
Publikováno v:
Nature Catalysis. 2:431-436
Compared to the vapour phase, liquid-phase heterogeneous catalysis provides additional degrees of freedom for reaction engineering, but the multifaceted solvent effects complicate analysis of the reaction mechanism. Here, using furfural as an example