Výsledky vyhledávání - "Umesh I Kaluarachchige Don"

Akademický článek

Studies Relevant to the Functional Model of Mo-Cu CODH: In Situ Reactions of Cu(I)-L Complexes with Mo(VI) and Synthesis of Stable Structurally Characterized Heterotetranuclear MoVI2CuI2 Complex

Autor: Umesh I. Kaluarachchige Don, Ahmad S. Almaat, Cassandra L. Ward, Stanislav Groysman

Publikováno v: Molecules, Vol 28, Iss 8, p 3644 (2023)

In this study, we report the synthesis, characterization, and reactions of Cu(I) complexes of the general form Cu(L)(LigH2) (LigH2 = xanthene-based heterodinucleating ligand (E)-3-(((5-(bis(pyridin-2-ylmethyl)amino)-2,7-di-tert-butyl-9,9-dimethyl-9H-

Externí odkaz: https://doaj.org/article/2dbd884da2394091962560d85e6844b8

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Synthesis and Cu(I)/Mo(VI) Reactivity of a Bifunctional Heterodinucleating Ligand on a Xanthene Platform

Autor: Richard L. Lord, Stanislav Groysman, Cassandra L. Ward, Umesh I Kaluarachchige Don, Thilini S. Hollingsworth, Sudheer S. Kurup

Publikováno v: Inorganic chemistry. 60(19)

In an effort to probe the feasibility of a model of Mo-Cu CODH (CODH = carbon monoxide dehydrogenase) lacking a bridging sulfido group, the new heterodinucleating ligand LH2 was designed and its Cu(I)/Mo(VI) reactivity was investigated. LH2 ((E)-3-((

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d8049cc2a25fe49d11bdae9bcf7d9c81
https://pubmed.ncbi.nlm.nih.gov/34520185

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