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pro vyhledávání: '"Ulysse Caniparoli"'
Autor:
Giuseppe Zuccarello, Leonardo J. Nannini, Ana Arroyo-Bondía, Nicolás Fincias, Isabel Arranz, Alba H. Pérez-Jimeno, Matthias Peeters, Inmaculada Martín-Torres, Anna Sadurní, Víctor García-Vázquez, Yufei Wang, Mariia S. Kirillova, Marc Montesinos-Magraner, Ulysse Caniparoli, Gonzalo D. Núñez, Feliu Maseras, Maria Besora, Imma Escofet, Antonio M. Echavarren
A new generation of chiral gold(I) catalysts based on variations of complexes with JohnPhos-type ligands with a remote C2-symmetric 2,5-diarylpyrrolidine have been synthesized with different substitutions at the top and bottom aryl rings: from replac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d065572de737b71d6aa7b772e972624e
https://doi.org/10.26434/chemrxiv-2023-vxlcf
https://doi.org/10.26434/chemrxiv-2023-vxlcf
Publikováno v:
ACS Catalysis
Planar chiral monodentate 1,3-disubstituted ferrocene phosphines inspired on JohnPhos-type ligands have been synthesized and applied to the enantioselective gold(I) catalyzed [4 + 2] cycloaddition of 1,6-arylenynes. Computational studies rationalized
Publikováno v:
Chempluschem
Gold(I) catalysts are ideal for the activation of alkynes under very mild conditions. However, unlike allenes or alkenes, the triple bond of alkynes cannot be prochiral. In addition, the linear coordination displayed by gold(I) complexes places the c