Výsledky vyhledávání - "Tyler M. Porter"

Full Conformational Analyses of the Ultrafast Isomerization in Penta-coordinated Ru(S2C2(CF3)2)(CO)(PPh3)2: One Compound, Two Crystal Structures, Three CO Frequencies, 24 Stereoisomers, and 48 Transition States

Autor: Tyler M. Porter, Hao Tang, Clifford P. Kubiak, Michael B. Hall

Publikováno v: Inorganic Chemistry. 59:11757-11769

The stereodynamics of an ultrafast (picosecond) isomerization in a penta-coordinated ruthenium complex, Ru(S2C2(CF3)2)(CO)(PPh3)2, were characterized by density functional theory (DFT). The rutheni...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::6a51391d6c82303972bb7ad0e92800b5
https://doi.org/10.1021/acs.inorgchem.0c01708

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Electronic Structural Studies of the Ru3(III,II,II) Mixed-Valent State of Oxo-Centered Triruthenium Clusters

Autor: Joseph M. Palasz, Tyler M. Porter, Clifford P. Kubiak

Publikováno v: Inorganic Chemistry. 59:10532-10539

The anionic state of basic ruthenium acetate complexes of the type [Ru3O(OAc)6](CO)(L1)(L2) (L = 4-cyanopyridine, pyridine, and N,N-dimethylaminopyridine) feature pronounced optical transitions in the near-infrared region indicative of strong

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::902c434467b517dcd132d8d050360537
https://doi.org/10.1021/acs.inorgchem.0c00881

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Thermodynamic targeting of electrocatalytic CO2 reduction: advantages, limitations, and insights for catalyst design

Autor: Clifford P. Kubiak, Tyler M. Porter, Andrew L. Ostericher, Mark H. Reineke

Publikováno v: Dalton Transactions. 48:15841-15848

Herein is reported the electrocatalytic reduction of CO2 with the complex [Ni(bis-NHC)(dmpe)]2+ (1) (bis-NHC = 1,l':3,3'-bis(1,3-propanediyl)dibenzimidazolin-2,2'-diylidene; dmpe = 1,2-bis(dimethylphosphino)ethane). The hydricity of 1 was previously

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7f88a57c612479549c72a7be678a9c0c
https://doi.org/10.1039/c9dt03255j

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Steric and electronic control of an ultrafast isomerization

Autor: Andrew L. Ostericher, Clifford P. Kubiak, Tyler M. Porter

Publikováno v: Chemical science, vol 10, iss 34

Synthetic control of the influence of steric and electronic factors on the ultrafast (picosecond) isomerization of penta-coordinate ruthenium dithietene complexes (Ru((CF3)2C2S2)(CO)(L)2, where L = a monodentate phosphine ligand) is reported. Seven n

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c750e33207ce31ce2535e8da679bc8b3
https://doi.org/10.1039/c9sc02359c

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Carbonate-promoted C-H carboxylation of electron-rich heteroarenes

Autor: Matthew W. Kanan, Tyler M. Porter

Publikováno v: Chemical Science

C–H carboxylation is an attractive transformation for both streamlining synthesis and valorizing CO2. The high bond strength and very low acidity of most C–H bonds, as well as the low reactivity of CO2, present fundamental challenges for this che

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ecdac83445e423fb6621ecdb0ec34345
https://pubmed.ncbi.nlm.nih.gov/34123214

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Full Conformational Analyses of the Ultrafast Isomerization in Penta-coordinated Ru(S

Autor: Hao, Tang, Tyler M, Porter, Clifford P, Kubiak, Michael B, Hall

Publikováno v: Inorganic chemistry. 59(16)

The stereodynamics of an ultrafast (picosecond) isomerization in a penta-coordinated ruthenium complex, Ru(S

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::d922be8269c008454c6772a76e0abe22
https://pubmed.ncbi.nlm.nih.gov/32799482

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Electronic Structural Studies of the Ru

Autor: Joseph M, Palasz, Tyler M, Porter, Clifford P, Kubiak

Publikováno v: Inorganic chemistry. 59(15)

The anionic state of basic ruthenium acetate complexes of the type [Ru

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::59410848c85ea7268dee92e274bc9729
https://pubmed.ncbi.nlm.nih.gov/32674565

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Stable Mixed-Valent Complexes Formed by Electron Delocalization Across Hydrogen Bonds of Pyrimidinone-Linked Metal Clusters

Autor: Tyler M. Porter, Gavin P. Heim, Clifford P. Kubiak

Publikováno v: Journal of the American Chemical Society. 140:12756-12759

Electron transfer across a mixed-valent hydrogen-bonded self-dimer of oxo-centered triruthenium clusters bridged by a pair of 4(3H)-pyrimidinones is reported. Spectroelectrochemical studies in methylene chloride reveal that 1 rapidly self-dimerizes u

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5aafbf4c951a2bc40a3b09159dff0a00
https://doi.org/10.1021/jacs.8b09273

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Symmetry-Breaking Charge Transfer in Boron Dipyridylmethene (DIPYR) Dimers

Autor: Jessica H. Golden, Abegail C. Tadle, John W. Facendola, Clifford P. Kubiak, Mark E. Thompson, Stephen E. Bradforth, M R Daniel Sylvinson, Laura Estergreen, Tyler M. Porter

Publikováno v: ACS Applied Energy Materials. 1:1083-1095

We recently reported the photophysical properties of boron dipyridylmethene (DIPYR) dyes, a class of intensely fluorescent pyridine-based chromophores, which are structural analogues of both acenes and BODIPYs. In this work, we endeavored to explore

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::42ae900a2b6f27db4e3fe57c1c42bd91
https://doi.org/10.1021/acsaem.7b00214

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