Zobrazeno 1 - 10
of 5 963
pro vyhledávání: '"Trigonal bipyramidal molecular geometry"'
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
Zaguán. Repositorio Digital de la Universidad de Zaragoza
instname
Zaguán. Repositorio Digital de la Universidad de Zaragoza
By using suitable synthetic procedures, we have first isolated the square-planar organosilver(III) compounds [PPh4][trans-(CF3)2AgX2] [X=Cl (1 a), Br (2 a)]. The geometry and stereochemistry of the chloro-derivative 1 a have been unambiguously establ
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2266e21a4f406f0dba449dfd97ff0377
https://doi.org/10.1002/anie.202112449
https://doi.org/10.1002/anie.202112449
Publikováno v:
Acta Chimica Slovenica, Vol 68, Iss 3, Pp 693-699 (2021)
By changing the anions of zinc salts, three different zinc(II) complexes, [Zn 2 (HL) 2 (NCS) 4 ]·2CH 3 OH ( 1 ), [Zn 2 L( μ 2 - η 1 : η 1 -CH 3 COO) 2 (NCS)] ( 2 ) and [Zn(HL)I 2 ]·CH 3 OH ( 3 ), where L = 5-bromo-2-((2-(diethylamino)ethylimino)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d1a81a99b037d628a3baa854ca5f87ee
https://doi.org/10.17344/acsi.2021.6716
https://doi.org/10.17344/acsi.2021.6716
Publikováno v:
Russian Journal of Coordination Chemistry. 47:626-630
In the crystal of [(2-MeO)(5-Cl)C6H3]3Bi (I), obtained from bismuth trichloride and 2-methoxy-5-chlorophenyllithium in ether, bismuth atoms have a trigonal ligand environment. The coordination number of the central atom is 6 (3 + 3), with allowance m
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::562a73592f4d88b9ad6ff1fb00ae49ac
https://doi.org/10.1134/s1070328421070058
https://doi.org/10.1134/s1070328421070058
Autor:
Hassan Ghani, Emad Yousif
Publikováno v:
Al-Nahrain Journal of Science. 24:9-15
Organotin compounds (OTCs) are characterized as having at minimum one covalent bond between carbon and tin atoms, and are usually denoted by the formula RnSnX4-n (n =1-3, R =aryl or alkyl, X =halogen ion or a carboxylate, etc.). There are several met
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e663fc77afc5fac2fe5ecab4b45a94ad
https://doi.org/10.22401/anjs.24.3.02
https://doi.org/10.22401/anjs.24.3.02
Autor:
Heng-Yu Qian
Publikováno v:
Acta Chimica Slovenica, Vol 68, Iss 3, Pp 638-644 (2021)
Two new tetranuclear zinc(II) complexes, [Zn 4 (L 1 ) 2 ( μ 2 - η 1 : η 1 -CH 3 COO) 4 ( μ 1,1 -N 3 ) 2 ] ( 1 ) and [Zn 4 (L 2 ) 4 (CH 3 CH 2 OH)(H 2 O)] ( 2 ), where L 1 and L 2 are the deprotonated forms of 4-fluoro-2-((pyridin-2-ylmethylimino)
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1853a57721c43919cc08a67582daece
https://journals.matheo.si/index.php/ACSi/article/view/6656
https://journals.matheo.si/index.php/ACSi/article/view/6656
Autor:
Heng-Yu Qian
Publikováno v:
Acta Chimica Slovenica, Vol 68, Iss 3, Pp 700-708 (2021)
Two new polynuclear zinc complexes [Zn 2 Br 2 (L 1 ) 2 ] ( 1 ) and [Zn( μ 1,5 -dca)L 2 ] n ( 2 ), and two new mononuclear cobalt(III) complexes [CoL 1 N 3 (Brsal)] ( 3 ) and [CoL 2 (HL 2 )] ( 4 ), where L 1 = 5-bromo-2-(((2-dimethylamino)ethyl)imino
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::41c0738efc1d0afd12321a4613493a65
https://journals.matheo.si/index.php/ACSi/article/view/6721
https://journals.matheo.si/index.php/ACSi/article/view/6721
Publikováno v:
Inorganic Chemistry. 60:12912-12923
New photoswitchable pyridyl-azo-phenyl-decorated tripodal host ligands (Laz) that belong to the cyclotriveratrylene family have been synthesized, and their photoswitching behavior and crystal structures determined. The latter includes a remarkable 7-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0a3874ad5d74d36721d4683a5fb32e96
https://doi.org/10.1021/acs.inorgchem.1c01297
https://doi.org/10.1021/acs.inorgchem.1c01297
Publikováno v:
Journal of Structural Chemistry. 62:1043-1055
Bithiazole is considered as a domain of bleomycin which is countered as a chemotherapeutic drug to treat many types of cancer. Hence, the trend towards the design of model compounds containing the bithiazole moiety is increased recently. In this rega
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3b0a13c443a8277c25463f251de642e5
https://doi.org/10.1134/s0022476621070088
https://doi.org/10.1134/s0022476621070088
Autor:
Pierre Le Magueres, Graham N. George, Timothy C. Johnstone, Monica Weng, Brent Lindquist-Kleissler
Publikováno v:
Inorganic chemistry, vol 60, iss 12
Pentaphenylantimony (SbPh5) has been previously crystallized in either a square pyramidal or trigonal bipyramidal geometry. Investigation of the solution-state structure of SbPh5 has been hampered by the extreme fluxionality of this compound, but pre
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2aa9f5bf1750988756ff452362302bbb
https://doi.org/10.1021/acs.inorgchem.1c00496
https://doi.org/10.1021/acs.inorgchem.1c00496
Publikováno v:
Chemical Science
Transfer reagents are useful tools in chemistry to access metastable compounds. The reaction of [Cp′′2ZrCl2] with KSb(SiMe3)2 leads to the formation of the novel polyantimony triple decker complex [(Cp′′Zr)2(μ,η1:1:1:1:1:1-Sb6)] (1, Cp′
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::18dae3c7fbe3f1685eeaa79eaa6ede9c
http://europepmc.org/articles/PMC8293801
http://europepmc.org/articles/PMC8293801