Výsledky vyhledávání - "Trevor F. Nolan"

A New Approach To Studying the Mechanism of Catalytic Reactions: An Investigation into the Photocatalytic Hydrogenation of Norbornadiene and Dimethylfumarate Using Polyethylene Matrices at Low Temperature and High Pressure

Autor: Gavin I. Childs, Andrew I. Cooper, Martyn Poliakoff, and Michael W. George, Trevor F. Nolan, Michael J. Carrott

Publikováno v: Journal of the American Chemical Society. 123:6857-6866

This paper presents a new method for investigating the mechanisms of homogeneously catalyzed reactions involving gases, particularly H2. We show how the combination of polyethylene (PE) matrices and high pressure−low temperature (HPLT) experiments

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a2c5a91096abc76a9986ecacfdfc4881
https://doi.org/10.1021/ja004345t

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Chemistry of Reactive Organometallic Compounds at Low Temperatures and High Pressures: Reactions of M(CO)6(M = Cr, Mo, W), (η6-C6H3Me3)M(CO)3(M = Cr and Mo), and W(CO)5CS with H2and N2in Polyethylene Matrices

Autor: Michael W. George, Trevor F. Nolan, Simon E. J. Goff, Martyn Poliakoff

Publikováno v: Organometallics. 17:2730-2737

An unusual high-pressure ( 30 K) cell is used to study the photochemistry of d6 metal carbonyl complexes and related compounds in a polyethylene (PE) matrix. This approach combines some of the advantages of traditional matrix isolation with those of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1276f7addf15b5a59b3cb8dc478f95c4
https://doi.org/10.1021/om970474f

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Unusual Structure and Reactivity of the Photogenerated Intermediate Cp*Cr(μ-CO)3CrCp* (Cp* = η5-C5Me5)

Autor: Trevor F. Nolan, James J. Turner, Ian G. Virrels, Michael W. George

Publikováno v: Organometallics. 16:5879-5883

Employing time-resolved IR spectroscopy, we have demonstrated that, following photolysis of [Cp*Cr(CO)2]2 (1) in n-heptane, the only initial photoproduct is the triply bridged CO-loss intermediate ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8766db8b6404f38dcfd02c45733135da
https://doi.org/10.1021/om970641b

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