Výsledky vyhledávání - "Trevor D. Lohrey"

Spectroscopic, Magnetic, and Computational Investigations on a Series of Rhenium(III) Cyclopentadienide β-diketiminate Halide and Pseudohalide Complexes

Autor: Robert G. Bergman, John Arnold, Laurent Maron, Daniel J. Lussier, Khetpakorn Chakarawet, Jorge Ivan Amaro Estrada, Trevor D. Lohrey, Erik T. Ouellette

Publikováno v: Organometallics
Organometallics, 2022, 41 (22), pp.3128-3137. ⟨10.1021/acs.organomet.1c00516⟩

International audience; The low-valent rhenium(I) salt Na[Re(η5-Cp)(BDI)] (BDI = N,N′-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate) was shown to react with various halide and chalcogenolate reagents, leading to the isolation of a series

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e5f638f2017baf1d47a39128601a061a
https://hal.science/hal-04117025

Zobrazit plný text záznamu

Thorium amidates function as single-source molecular precursors for thorium dioxide

Autor: Matthew A. Marcus, A. L. David Kilcoyne, David K. Shuh, Trevor D. Lohrey, John Arnold, Erik T. Ouellette, Mark D. Straub, Jacob A. Branson, Stefan G. Minasian, Michael A. Boreen, Alex Ditter, José Ramirez, Maria Paley

Publikováno v: Chemical Communications. 57:4954-4957

We report the synthesis of four homoleptic thorium(iv) amidate complexes as single-source molecular precursors for thorium dioxide. Each can be sublimed at atmospheric pressure, with the substituents on the amidate ligands significantly impacting the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0f623753c340324a14bcfed306d77c1f
https://doi.org/10.1039/d1cc00867f

Zobrazit plný text záznamu

σ or π? Bonding interactions in a series of rhenium metallotetrylenes

Autor: Robert G. Bergman, John Arnold, Iskander Douair, I Joseph Brackbill, Erik T. Ouellette, Laurent Maron, Trevor D. Lohrey, Ambre Carpentier

Publikováno v: Dalton Transactions
Dalton Transactions, 2021, 50 (6), pp.2083-2092. ⟨10.1039/d1dt00129a⟩

International audience; Salt metathesis reactions between a low-valent rhenium(I) complex, Na[Re(eta(5)-Cp)(BDI)] (BDI = N,N'-bis (2,6-diisopropylphenyl)-3,5-dimethyl-beta-diketiminate), and a series of amidinate-supported tetrylenes of the form ECI[

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::261842dad293ae341086b6862d223a9f
https://doi.org/10.1039/d1dt00129a

Zobrazit plný text záznamu

Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes

Autor: Trevor D. Lohrey, Dallas D. Reilly, Mark Kalaj, Robert G. Surbella, Bruce K. McNamara, Korey P. Carter, Jon M. Schwantes, Rebecca J. Abergel

Publikováno v: Chemistry – A European Journal. 26:13819-13825

A new uranyl containing metal-organic framework, RPL-1: [(UO2)2(C28H18O8)] . H2O (RPL for Radiochemical Processing Laboratory), was prepared, structurally characterized, and the solid-state photoluminescence properties explored. Single crystal X-ray

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1bbdef396d3c521498655e7e781187bd
https://doi.org/10.1002/chem.201905766

Zobrazit plný text záznamu

Plný text ve formátu HTML

Access to Corrole-Appended Persubstituted Benzofurans by a Multicomponent Reaction: The Dual Role of p-Chloranil

Autor: Maciej Krzeszewski, Beata Koszarna, Daniel T. Gryko, John Arnold, Agnieszka Nowak-Król, Trevor D. Lohrey

Publikováno v: Organic letters, vol 22, iss 20
Organic Letters

A multicomponent reaction among dipyrranes, aryl-propargyl aldehydes, and p-chloranil leading to 10-(benzofuran-2-yl)corroles is described. p-Chloranil was identified as a crucial reagent playing a twofold role: an oxidant taking part in the formatio

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa768b9250ca4b2eea0f5e960bc1ac2d
https://doi.org/10.1021/acs.orglett.0c03133

Zobrazit plný text záznamu

Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts

Autor: Robert G. Bergman, Guodong Rao, John Arnold, Erik T. Ouellette, Trevor D. Lohrey, R. David Britt, David W. Small

Publikováno v: Journal of the American Chemical Society. 142:13805-13813

Electron paramagnetic resonance (EPR) studies of the rhenium(II) complex Re(η5-Cp)(BDI) (1; BDI = N,N′-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate) have revealed that this species revers...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd8eddf216a348cefc0118c19112718b
https://doi.org/10.1021/jacs.0c04719

Zobrazit plný text záznamu

Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions

Autor: Robert G. Bergman, Emmanuel A. Cortes, Jade I. Fostvedt, Alexander K. Oanta, John Arnold, Trevor D. Lohrey, Anukta Jain

Publikováno v: Inorganic Chemistry. 59:11096-11107

We present a wide range of reactivity studies focused on the rhenium(V) oxo imido complex (DippN)(O)Re(BDI) (1, Dipp = 2,6-diisopropylphenyl and BDI = N,N'-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate). This complex, which was previously s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::83f62e6b521f8ca360ec7c4b9bdcd550
https://doi.org/10.1021/acs.inorgchem.0c01589

Zobrazit plný text záznamu

Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes

Autor: John Arnold, Robert G. Bergman, Trevor D. Lohrey, Emmanuel A. Cortes

Publikováno v: Inorganic Chemistry. 59:7216-7226

We report the synthesis and reactivity studies of a pair of rhenium(V) oxo imido complexes. Oxidation of the rhenium(III) terminal oxo ORe(η2-DHF)(BDI) (DHF = dihydrofulvalene, BDI = N,N′-bis(2,6-d...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a81c956487e2efb3896d2adfafa6d626
https://doi.org/10.1021/acs.inorgchem.0c00658

Zobrazit plný text záznamu

1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes

Autor: Benjamin M. Kriegel, Lauren N. Grant, Trevor D. Lohrey, Andreas H. Obenhuber, John Arnold, Jade I. Fostvedt, Robert G. Bergman

Publikováno v: Chemical Science

The bis(imido) complexes (BDI)Nb(NtBu)2 and (BDI)Nb(NtBu)(NAr) (BDI = N,N′-bis(2,6-diisopropylphenyl)-3,5-dimethyl-β-diketiminate; Ar = 2,6-diisopropylphenyl) were shown to engage in 1,2-addition and [2 + 2] cycloaddition reactions with a wide var

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dd142f5c9915dad83cc82f8bb27607cc
https://doi.org/10.1039/d0sc03489d

Zobrazit plný text záznamu

Identifying the Imperative Role of Metal–Olefin Interactions in Catalytic C–O Reductive Elimination from Nickel(II)

Autor: Trevor D. Lohrey, William A. Goddard, Brian M. Stoltz, Alexander Q. Cusumano

Publikováno v: ACS Catal

We present a series of experimental and computational mechanistic investigations of an unusually facile example of Ni-catalyzed C–O bond formation. Our method, originally reported in 2016, involves the formation of cyclic enol ethers from vinyl iod

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bf87520eec29249dab7510535c60a151
https://resolver.caltech.edu/CaltechAUTHORS:20210821-142512577

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání